通过电凝凝,再生带有As(V) 的颗粒状活性炭
Niels Michiel Moed1, Young Ku1, Ting-Hsuan Hsu1
1Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei, Taiwan, ROC.
概括
这项研究表明,用NaCl化电凝能有效再生 (As(V)) 加载的活性炭,达到高达93%的再生. 这种方法是可扩展和高效的多个周期.
科学领域:
- 环境科学 环境科学
- 水处理技术 水处理技术
- 材料科学 材料科学 材料科学
背景情况:
- 颗粒活性炭 (GAC) 广泛用于从水中去除 (As(V)).
- 消耗的GAC的再生对于可持续和经济有效的水处理至关重要.
- 开发高效的再生方法,以As(V) 装载的GAC是一个持续的挑战.
研究的目的:
- 通过使用电凝 (EC) 辅助化 (NaCl) 溶解来研究带有As(V) 荷载的GAC的再生.
- 为了优化再生参数,如pH值,电流密度,时间和NaCl度.
- 评估再生过程的可扩展性和可重复使用性.
主要方法:
- 带有V的GAC在电化学电池中经过了电凝.
- 使用不同度的NaCl溶液进行了化.
- 在不同的运行条件下评估了再生效率 (pH,电流密度,时间,Fe (II) 添加).
- 重复吸附-脱附周期以评估长期性能.
主要成果:
- 最佳的As(V) 吸附到GAC发生在pH 6时,而脱附在pH 11和3时是最高的.
- 再生效率随着电流密度和时间的增加而增加,达到85%.
- 添加6000mg/L的NaCl显著改善了再生,达到92%-93%.
- 该过程表现出极好的可扩展性,在高GAC度下,效率下降最小.
- 在经过四个再生周期后,高再生效率 (81-82%) 保持不变.
结论:
- 电凝与NaCl化相结合是一种高效的方法,用于再生As(V) 负载的GAC.
- 在再生过程中提高化效率,NaCl度至关重要.
- 开发的方法提供了一个可扩展,高效和可重复使用的方法,用于在去除中进行GAC再生.
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