作为离子电池的阴极材料,Fe修饰的纳西康型Na3V2(PO4) 3作为离子电池的阴极材料
Shuling Liu1,2, Zheng Xu1,2, Lei Ren1,2
1College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology Xi'an 710021 China liushuling@sust.edu.cn jianbotong@aliyun.com.
RSC advances
|February 6, 2024
概括
一种新的NASICON类型材料Na3Fe0.8V1.2(PO4) 3 / C被合成用于离子电池. 这种化合物表现出极好的速度能力和循环稳定性,使其成为储能应用的有希望的候选者.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 固态化学 固态化学
背景情况:
- 离子电池 (SIB) 是离子电池的有希望的替代品,因为的丰富含量.
- 开发高性能阴极材料对于推进SIB技术至关重要.
研究的目的:
- 为了合成和描述一种新的纳西康类化合物,Na3Fe0.8V1.2(PO4) 3 / C (NFVP / C),用于SIB应用.
- 为了评估NFVP/C作为阴极材料的电化学性能.
主要方法:
- 用于NFVP/C制备的sol-gel合成方法.
- 用于晶体结构分析的X射线衍射 (XRD).
- 电化学测试,包括速率能力和循环性能.
主要成果:
- NFVP/C 呈现出 NASICON 类型的晶体结构,具有特定的单元细胞尺寸.
- Na‖NFVP/C电池显示出3.43V的放电潜力,而Na+/Na.
- 在40C时达到76.2mA hg-1的速率能力,在5C时500个循环后保持97.8%的容量.
结论:
- NFVP/C表现出卓越的电化学性能,包括高速率能力和长期循环稳定性.
- 该材料的卓越效率归因于增强的Na+导电性和减少的离子扩散能量障碍.
- 纳西康型Na3Fe0.8V1.2(PO4) 3 / C是下一代离子电池的一个非常有前途的阴极材料.
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