CeO2用于调节-双金属化物的电子结构,以促进高效的整体水分裂
Yutong Li1, Jianhui Yi1, Ruige Qin1
1Key Laboratory of Automobile Materials, Ministry of Education and School of Materials Science and Engineering, Jilin University, Changchun 130022, China.
Journal of colloid and interface science
|February 6, 2024
概括
地球上丰富的过渡金属化物为绿色生产提供了与相比具有成本效益的替代品. 这项研究引入了一种新的CeO2-修改的,,双金属化催化剂,具有增强的水分裂活性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 绿色化学 绿色化学
背景情况:
- 和是昂贵的贵金属,目前作为电催化剂用于整体水分裂.
- 开发大量的,具有成本效益的电催化剂对于绿色生产的广泛采用至关重要.
- 过渡金属化物是有前途的候选物,因为它们的稳定性,低成本和催化活性.
研究的目的:
- 为了合成和表征一种新的地球丰富的电催化剂,用于高效的整体水分.
- 为了提高催化性能,研究CeO2和合金双金属化物之间的电子相互作用.
- 评估开发材料的双功能催化活性,用于进化和氧进化反应.
主要方法:
- 电化学沉积 CeO2 在一个,,双金属化物核心外的纳米针结构上.
- X射线光电子光谱 (XPS) 用于表面分析和元素组成.
- 密度函数理论 (DFT) 计算以了解电子结构和吸附能.
- 在1M KOH中进行电化学测试,以检测演变反应 (HER) 和氧演变反应 (OER) 的性能.
主要成果:
- 一种由CeO2和二金属化物 (CoP3) 组成的花样,核心外的纳米针催化剂被成功合成.
- XPS和DFT计算显示了CeO2和CoP3之间的电子合和转移,优化了催化剂的电子结构.
- 催化剂在50mA cm-2在1M KOH中显示了HER的109mV和OER的296mV的低超电位.
- 作为一个双功能催化剂,它只需要1.77V才能达到50 mA cm-2的总体水分裂.
结论:
- 经CeO2修改的双金属化物催化剂对整体水分的活性显著增强.
- CeO2和CoP3之间的协同电子效应是减少吸附能量和提高催化效率的关键.
- 这种地球上丰富的双功能催化剂显示出成本效益高的绿色生产的巨大潜力.
更多相关视频
08:40Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
3.6K
05:47Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
7.7K
相关概念视频
02:42Valence Bond Theory
8.6K
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
8.6K
02:58Crystal Field Theory - Octahedral Complexes
26.5K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
26.5K
02:34Structural Isomerism
19.2K
Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...
19.2K
03:02Colors and Magnetism
11.7K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
11.7K
02:58Properties of Transition Metals
25.9K
Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
25.9K