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耐火化合物的电化学氧化来自热水碳化工艺水中的耐火化合物
1Technical University of Darmstadt, Institute IWAR, Franziska-Braun-Str. 7, 64287, Darmstadt, Germany.
Chemosphere
|February 6, 2024
概括
电化学氧化有效地处理水热碳化 (HTC) 工艺水,消除超过97%的化学氧气需求 (COD). 这种方法矿化了耐火,显示了污泥处理和潜在的回收的前景.
科学领域:
- 环境工程 环境工程
- 水处理技术水处理技术
- 电化学 电化学 电化学
背景情况:
- 水热碳化 (HTC) 是一种正在发展中的污水污泥处理技术.
- HTC工艺用水含有不可生物降解的碳和类污染物,需要有效的处理解决方案.
- 有效的工艺水管理对于HTC对污水污泥的全面实施至关重要.
研究的目的:
- 为了研究电化学氧化 (EO) 对于处理HTC工艺水的有效性.
- 将EO性能与不同的生物预处理进行比较:没有,化学氧需求 (COD) 移除,化/脱化.
- 评估COD去除,矿化,能源消耗和毒性降低.
主要方法:
- 电化学氧化 (EO) 使用添加的钻石电极.
- 用三种不同的预处理策略处理HTC工艺水.
- 对COD,有机和无机物种 (NO3-N,NH4-N) 和Vibrio fischeri毒性的分析.
主要成果:
- 在所有测试的HTC工艺水中,EO实现了97%以上的COD去除.
- 有机和耐火被完全矿化成酸盐 (NO3-N).
- 观察到 (NH4-N) 和酸盐 (NO3-N) 的高度,表明回收的潜力.
结论:
- 电化学氧化是一种可行的技术来处理HTC工艺水,特别是在生物预处理后去除COD.
- 处理后获得的高度可能对回收应用有价值.
- 氧化显著降低了HTC工艺水的毒性,提高了其环境安全性.
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