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Low-energy Cathodoluminescence for OxyNitride Phosphors
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提高效率,扩大刺激和定制的Er3+发光由Te4+在Cs2NaYbCl6晶体中的Codoping触发,用于多功能应用
Xi Chen1, Yuexiao Pan1, Yihong Ding1
1Key Laboratory of Carbon Materials of Zhejiang Province, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China.
Inorganic chemistry
|February 7, 2024
概括
研究人员在用 (Er3+) 和 (Te4+) 添加 (Er3+) 的乙 (CNYC) 晶体中探索了可调节的发光. 这项工作提高了发光材料效率和光电子设备和温度传感器的颜色调整.
科学领域:
- 材料科学 材料科学 材料科学
- 化学 化学 化学
- 固态物理 固态物理
背景情况:
- 研究重点是开发高效和可调节的发光材料.
- 用Er3+添加剂的材料因其发光特性而引起人们的兴趣.
- 对环境无害的矿Cs2NaYbCl6 (CNYC) 是一个有希望的宿主材料.
研究的目的:
- 为了研究CNYC晶体中Er3+离子的发光特性,这些晶体与Te4+.
- 为了提高发光效率和调整辐射颜色.
- 探索在光电子和温度传感领域的潜在应用.
主要方法:
- 合成了Cs2NaYbCl6晶体,这些晶体含有不同度的Er3+和Te4+.
- 具有特征的发光特性,包括激发和发射光谱.
- 进行理论计算以了解激发机制.
主要成果:
- 通过调整剂度和Te4+诱导的缺陷,通过调整Er3+的可调节绿色和红色排放.
- 确定了f-f过渡作为Er3+中的多刺激激发的起源.
- 证明了扩大激发,颜色调和增强的发光效率.
结论:
- CNYC:Te4+,Er3+晶体表现出可调节的发光,适用于先进的光电子设备.
- 可调节的发光对温度的反应表明了温度传感应用的潜力.
- 与Te4+的配合有效地增强和调整了CNYC中的Er3+的发光.
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