棉纤维在理过程中的机械性能和物理化学特性
Yuhua Shi1, Liuyuan Geng1, Pengwei Fan1
1Collage of Mechanical and Electrical Engineering, Tarim University, Alar, Xinjiang 843300, China; Modern Agricultural Engineering Key Laboratory at Universities of Education Department of Xinjiang Uygur Autonomous Region, Alar, Xinjiang 843300, China.
International journal of biological macromolecules
|February 7, 2024
概括
棉纤维最初会增强机械性能和结晶性,但延长加工会导致表面损伤和由于纤维素链断裂而降低强度. 这在原子层面影响了纤维质量.
科学领域:
- 材料科学 材料科学 材料科学
- 织工程 织工程 织工程
- 物理化学 物理化学
背景情况:
- 棉纤维质量对于织应用至关重要.
- 了解机械加工对纤维特性的影响对于优化织品生产至关重要.
- 以前的研究还没有完全阐明理过程中棉纤维的原子级变化.
研究的目的:
- 分析理过程中棉纤维的机械性能和表面损伤.
- 为了研究由于机械损坏而导致的原子级物理和化学性质变化.
- 为了将理引起的变化与纤维强度和结晶性相关联.
主要方法:
- 棉纤维的实验分析 (原棉,第一,第二,第三理棉).
- 分子动力学模拟用于研究原子级相互作用.
- 测量破裂强度和X射线衍射的晶度 (CrI).
主要成果:
- 机械性能和结晶性最初增加,然后随着连续的理而下降.
- 表面撕裂增加,而C-O结合能降低.
- 断裂强度有所变化: +7.4% (第一个CC), -11% (第二个CC), -7.7% (第三个CC).
- 结晶度: 70.8% (RC),75.3% (第一个CC),72.7% (第二个CC),71.8% (第三个CC).
- 理在无形区域中破坏了C-O和C-C键,导致纤维素链断裂和强度降低.
结论:
- 理会导致棉纤维结构和特性发生显著变化.
- 优化理是必要的,以平衡改善的纤维对齐与最小化机械损坏.
- 原子级键变化解释了理棉纤维中观察到的宏观性质变化.
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