基于富里埃变换红外光谱学结合SCARS-DNNN的多组分SF6分解产品的定量检测
Guangwen Shi1, Jie Gao1, Xinyu Zhang1
1School of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
|February 8, 2024
概括
使用富里埃变换红外光谱 (FTIR) 和SCARS深度神经网络 (SCARS-DNN) 的新方法,可以快速,非破坏性地检测气体绝缘开关设备 (GIS) 中的硫六化物 (SF) 分解产物. 这种方法显著提高了评估绝缘状况的准确性.
科学领域:
- 电气工程 电气工程
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 对SF6分解产物的准确分析对于评估气体绝缘开关装置 (GIS) 的内部绝缘状态至关重要.
- 现有的方法可能面临来自背景SF6气体干扰的挑战,需要高效的定量校准模型.
研究的目的:
- 提出一种快速,非破坏性的定量校准模型,用于检测SF6分解产品.
- 开发和评估一种将富里埃变换红外光谱法 (FTIR) 与稳定性竞争性自适应重量化采样深度神经网络 (SCARS-DNN) 结合在一起的模型.
主要方法:
- 使用兰伯特-比尔定律消除SF6背景干扰.
- 基线校正和Savitzky-Golay (S-G) 调整用于降低噪声.
- 蒙特卡洛交叉验证用于异常检测,其次是非信息变量消除 (UVE) 和特征选择的SCARS,导致FULL-DNN,UVE-DNN和SCARS-DNN模型.
主要成果:
- 该SCARS-DNN模型表现出优异的预测性能,其根平均平方误差 (RMSE) 降低了96.18%,平均绝对百分比误差 (MAPE) 降低了96.11%.
- 预测三个分解产品的相对误差保持在1.36%以下,即使存在显著的SF干扰.
- 开发的模型有效地处理了背景气体干扰和噪声.
结论:
- 该SCARS-DNN模型非常适合高精度定量检测SF6分解气体.
- 这种方法为GIS绝缘状态的非破坏性评估提供了一种可靠的方法.
- FTIR与先进的机器学习技术的整合为气体分析提供了一个强大的工具.
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