通过高性能K离子电池的粘合调节,打破低应变和深化合金阳极的权衡
En Zhou1, Xiao Luo1, Hongchang Jin1
1Hefei National Research Center for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Applied Chemistry, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China.
Journal of the American Chemical Society
|February 9, 2024
概括
单原子修饰稳定离子电池的合金阳极. 在黑色阳极中使用硫可以创建一个强大的网络,增强稳定性,并使深层储存提供更长的电池寿命.
科学领域:
- 材料科学
- 电化学
- 能量储存
背景情况:
- 合金阳极由于其高理论容量,对储存具有前景.
- 深度化会导致这些阳极的结构应变,电极碎片化和K合金反应不良.
- 较大的K离子尺寸加剧了平衡低应变和深的挑战.
研究的目的:
- 使用化学结合调制处理合金阳极的体积膨胀.
- 提高离子电池阳极的稳定性和性能.
主要方法:
- 在黑 (BP) 中采用单原子修饰,以创建强大的 P-S 协同键网络.
- 研究了这种网络对机械性能和化物形成能量的影响.
- 评估了离子电池中修改的BP阳极的电化学性能.
主要成果:
- P-S共价键网络显著提高了K-P化合物的模量74%,改善了应变耐受性.
- 降低酸的形成能量促进了更深的化.
- 经过修改的BP阳极显示出高可逆容量,延长运行寿命和高面积容量.
结论:
- 通过单原子修饰进行化学结合调制是一种有效的策略,以克服合金阳极的低张力/深化权衡.
- 这种方法为开发高能稳定的离子电池提供了新的视角.
- 开发的PS共价网络在循环过程中为合金阳极提供了持续的稳定性.
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