光和热驱动的柔性固体超分子聚合物显示光和可逆光色
Wen-Wen Xu1, Yong Chen1, Xiufang Xu1
1College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|February 9, 2024
概括
灵活的超分子聚合物表现出可逆光色和长寿命的光. 这些材料对光和热有反应,提供可调节的发光和改变颜色的特性.
科学领域:
- 高分子聚合物化学的超分子化学
- 材料科学 材料科学 材料科学
- 摄影化学的使用.
背景情况:
- 开发具有可调节光学特性的先进材料至关重要.
- 具有光响应和发光特性的柔性聚合物具有显著的兴趣.
- 超分子化学为设计功能性材料提供了多功能策略.
研究的目的:
- 构建一种新的光和热驱动的柔性超分子聚合物.
- 研究其具有可逆长寿命光和光染色的特性.
- 探索控制这些现象的潜在机制.
主要方法:
- 合成烯胺共聚合物与4-烯衍生物的合成 (P-CN,P-oM,P-mM).
- 使用硫乙-β-环氧化 (SBCD) 和聚乙烯醇 (PVA) 形成超分子聚合物.
- 光寿命,光色行为和热回收的表征.
主要成果:
- 与母固体聚合物相比,超分子聚合物显著提高了光寿命.
- 在光照照射和加热后观察到光强度和寿命的可逆变化.
- 可见的光色变化 (P-CN 暗绿色,P-oM/P-mM 粉红色) 伴随着光变化.
- 通过热处理实现了性能恢复.
结论:
- 构建的灵活的超分子聚合物表现出高效和可逆的光色学和长寿命的光.
- 超分子组件内的静电相互作用和键增强了光.
- 观察到的现象归因于4-phenylpyridinium衍生物中有机基的生成和消失.
- 这些材料在可调节发光和光色装置中具有应用潜力.
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