追踪合体二氧化颗粒,以评估它们在剪切力应用下的缩悬浮中的分散和相互作用
Mohazzam Saeed1, Akira Otsuki2, Michiel Hermes3
1Minerals and Metallurgical Engineering, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, Luleå, Sweden.
Electrophoresis
|February 9, 2024
概括
分析了缩的合化二氧化悬浮物的相互作用. 观察到超出DLVO理论的意想不到的吸引力,受pH和剪切的影响,影响粒子分散.
科学领域:
- 合体和表面科学科学
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
背景情况:
- 合体二氧化悬浮剂在各种工业应用中广泛使用.
- 了解粒子相互作用对于控制悬浮特性至关重要.
- 像DLVO这样的现有理论可能无法完全捕捉集中系统中的复杂相互作用.
研究的目的:
- 为了描述缩的合性化悬浮中的粒子间相互作用.
- 为了研究剪切速率和pH对粒子分散的影响.
- 为了确定与DLVO理论的偏差,并探索非DLVO相互作用.
主要方法:
- 使用了Rheo-confocal显微镜和成像技术.
- 使用图像分析来确定粒子坐标和粒子间距离.
- 通过粒子直径 (H/D) 规范的表面对表面距离被计算和建模.
主要成果:
- 颗粒分布和H/D随着切割速度的增加而变化.
- 对一些粒子来说,实验测量的H/D比理论预测的H/D要短,这表明有吸引力.
- 非DLVO相互作用,包括对潜力和水力动力相互作用,是显著的,并且取决于pH和剪切.
结论:
- 这项研究揭示了状颗粒之间的意想不到的吸引力.
- 建议对H/D现有模型进行修改,并进行了验证.
- pH 和剪切强度是控制合体二氧化分散和凝结的关键因素.
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