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用于模具内涂层的热塑性聚氨电极粘合剂的合成和特征评估

Suk-Min Hong¹, Hyuck-Jin Kwon¹, Jung-Min Sun¹

¹Department of Chemistry, College of Science and Technology, Dankook University, Cheonan 31116, Republic of Korea.

|February 10, 2024

概括

这项研究开发了一个新的聚氨 (PU) 系列用于电极结合剂. 该材料在拉伸后显示出出色的机械强度,耐热性和稳定的电气性能,使其适用于模具内涂层应用.

科学领域:

聚合物科学聚合物科学
材料科学材料科学材料科学
电化学电化学电化学

背景情况:

聚氨 (PU) 是具有可调节性质的多功能聚合物.
开发先进的电极结合剂对于灵活的电子和储能设备至关重要.
模具内涂层需要具有高机械完整性和电导率的粘合剂.

研究的目的:

使用特定的单体合成和表征一种新的聚氨系列 (PHEI-PU).
评估合成的PUs的机械,热和电性能.
评估PHEI-PU作为用于模具内涂层应用的电极粘合剂的适用性.

主要方法:

六甲二酸 (HDI),聚碳酸二醇 (PCD) 和异酸衍生物 (ISBD) 的一次性批量聚合.
使用通用测试机 (UTM) 进行机械测试.
通过热重力测量分析 (TGA) 和差分扫描热度计 (DSC) 进行热分析.
用PU和银片制造电极,然后进行四点探针电测和扫描电子显微镜 (SEM) 进行分散分析.

主要成果:

PHEI-PU系列的机械性能非常出色,平均拉力强度为44.71MPa,破裂时延伸率为190%.
热分析证实了良好的耐热性.
使用PHEI-PU结合剂制造的电极在50%的延长后,表现出不到20%的电阻变化率,并且银片分散得很好.

结论:

合成的PHEI-PU系列具有卓越的机械和热性能.
该材料表现出了显著的电稳定性和良好的分散特性,当作为电极粘合剂使用时.
由于其全面的性能配置,PHEI-PU是模具内涂层中电极粘合剂应用的有前途的候选者.

关键词:

电极绑定器电极绑定器埃托克西异 sor 化物.在模具内涂层.聚碳酸二醇是多碳酸二醇的一种.聚氨是一种聚氨.

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