在硫电池中,万合一的雅努斯共价有机框架分离器作为快速的核和多硫化物催化剂
Hanyan Wu1, Ming Jiang2, Xuejie Gao1
1Center for Lignocellulosic Chemistry and Biomaterials, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China.
Journal of colloid and interface science
|February 10, 2024
概括
集成到分离器中的共价有机框架 (COF) 加快了核和-硫 (Li-S) 电池中的硫转化. 这一创新提高了Li-S电池的性能和周期寿命,用于实际应用.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 硫 (Li-S) 电池面临着诸如航天飞机效应,缓慢动力学和树突等挑战.
- 已知共价有机框架 (COF) 可以减轻穿效应,但它们在核和硫转化中的作用尚未得到充分探索.
研究的目的:
- 为快速充电Li-S电池开发一个集成的COF分离器 (TpPa@2400).
- 研究COF分离器作为快速核和硫种催化剂的功能.
主要方法:
- 密度函数理论 (DFT) 计算以确定吸附能量和巴德电荷.
- 制造和测试具有集成COF分离器的Li-Li对称电池和Li-S电池.
主要成果:
- TpPa@2400促进了优先的原子吸附和更快的运输,增强了离子核化.
- DFT的计算表明,TpPa@2400降低了硫种相互转换的自由能量障碍.
- -对称电池实现了6000小时的循环寿命;-S电池显示出高容量 (1636.4 mAh/g在0.1C) 和快速转换 (513.8 mAh/g在2C).
结论:
- 集成的TpPa@2400 COF 分离器有效促进核化,并催化硫转化.
- 这种COF分离器显著改善了Li-S电池的循环寿命和快速充电能力.
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