没有方向性的离子结合促进了矿太阳能电池的高效接口桥梁.
Lulan Chen1, Letian Chen1, Zijing Chen2
1Institute of New Energy Material Chemistry, School of Materials Science and Engineering, Renewable Energy Conversion and Storage Center, Nankai University, Tianjin, 300350, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|February 11, 2024
概括
离子通过形成离子键来促进矿太阳能电池被动化,使分子旋转成为可能,以减少缺陷和提高效率. 这种离子坐标协同作用提高了设备的性能和稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
- 太阳能光伏发电是如何实现的
背景情况:
- 对矿太阳能电池 (PSC) 来说,接口被动化至关重要,以尽量减少缺陷和离子迁移.
- 现有的易斯酸被动化策略需要精确的分子导向,限制分子选择.
- 由于导向约束,PSC中的埋面接口对有效的被动化提出了挑战.
研究的目的:
- 研究矿太阳能电池的新型被动化策略,利用离子结合.
- 探索离子在促进接口被动化的作用.
- 通过解决接口缺陷来提高矿太阳能电池的效率和稳定性.
主要方法:
- 研究了离子在矿结构中的迁移.
- 在矿界面分析了K-Ix离子键的形成.
- 研究了离子结合,分子骨干旋转和与Pb的极群化之间的相互作用.
主要成果:
- 离子与形成方向独立的离子键 (K-Ix),使分子旋转成为可能.
- 这促进了与Pb的基化,在埋藏的接口上形成了一个闭环结构.
- 实现了高PSC效率超过24.5% (0.09厘米2),迷你模块效率达到21% (12.4厘米2).
结论:
- 协同作用的离子坐标键有效地使矿太阳能电池接口无能化.
- 该策略减少了缺陷,修改了电场,并使固定不动,消除了hysteresis.
- 为提高PSC性能和稳定性提供了一个新的分子设计准则.
相关概念视频
P-N junction
533
A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
533
Valence Bond Theory and Hybridized Orbitals
19.4K
According to valence bond theory, a covalent bond results when: (1) an orbital on one atom overlaps an orbital on a second atom, and (2) the single electrons in each orbital combine to form an electron pair. The strength of a covalent bond depends on the extent of overlap of the orbitals involved. Maximum overlap is possible when the orbitals overlap on a direct line between the two nuclei.
A σ bond (single bond in a Lewis structure) is a covalent bond in which the electron density is...
A σ bond (single bond in a Lewis structure) is a covalent bond in which the electron density is...
19.4K
Ionic Bonds
118.4K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.4K
Ionic Bonding and Electron Transfer
41.6K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.6K
Hybridization of Atomic Orbitals I
47.1K
The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
47.1K
MO Theory and Covalent Bonding
10.5K
The molecular orbital theory describes the distribution of electrons in molecules in a manner similar to the distribution of electrons in atomic orbitals. The region of space in which a valence electron in a molecule is likely to be found is called a molecular orbital. Mathematically, the linear combination of atomic orbitals (LCAO) generates molecular orbitals. Combinations of in-phase atomic orbital wave functions result in regions with a high probability of electron density, while...
10.5K


