使用氧化还原穿机关闭电池,以确保安全高效的回收利用
Riho Mikita1, Akitoshi Suzumura2, Hiroki Kondo2
1Toyota Central R&D Laboratories, Inc., Nagakute, Aichi, 480-1192, Japan. e4796@mosk.tytlabs.co.jp.
Scientific reports
|February 11, 2024
概括
安全回收离子电池 (LIB) 通过新的氧化还原穿 (RS) 停用方法得到了改进. 这种技术可以安全地排出LIBs,并增强的收集,以实现可持续的电池回收.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 可持续化学 可持续化学
背景情况:
- 使用过的离子电池 (LIB) 的安全回收需要有效的停用.
- 像外部短路这样的传统方法对受损或合金LIB无效,构成安全风险.
研究的目的:
- 开发一种新,安全和有效的消耗LIB的停用方法.
- 解决电气完整性受到损害的LIB常规禁用技术的局限性.
主要方法:
- 在LIBs中引入具有特定氧化还原潜力的氧化还原穿车 (RSs).
- 电化学诱导内部短路使用RSs如铁或phenothiazine.
- 监测放电过程和溶解/重新沉积.
主要成果:
- 拟议的RS方法有效地将完全充电的LIB释放到大约0V.
- RSs促进了从负电极中沉积的的溶解.
- 离子有效地返回正极,改善收集率.
结论:
- 氧化还原穿停用方法为已耗尽的LIB回收提供了更安全的替代方案.
- 这种方法提高了电池回收过程中的安全性和收集效率.
- 该方法促进了离子电池生命周期的整体可持续性.
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