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Atomic Nuclei: Nuclear Magnetic Moment00:59

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All atomic nuclei are positively charged. When they have a nonzero spin, they behave like rotating charges. As a consequence of their charge and spin, these nuclei generate a magnetic field (B). This, in turn, gives rise to a magnetic moment (μ), which is randomly oriented in the absence of an external magnetic field. When an external magnetic field (B0) is applied, the magnetic moment vectors can align with the field or against it in 2 + 1 orientations. A hydrogen nucleus, which is just a...
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NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of...
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Atomic Nuclei: Nuclear Relaxation Processes01:23

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In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis,  the precessing magnetic moments are randomly oriented around the z-axis.
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Diamagnetism01:26

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Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
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Atomic Nuclei: Magnetic Resonance01:05

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The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external magnetic field, as the spins precess at the Larmor frequency, the excess population results in a net magnetization oriented along the z axis. When a pulse or a short burst of radio waves at the Larmor frequency is applied along the x axis, the coupling of frequencies causes resonance and flips the nuclear spins of the excess population from the...
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Atomic Nuclei: Nuclear Spin01:08

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All atomic particles possess an intrinsic angular momentum, or 'spin'. Electrons, protons, and neutrons each have a spin value of ½, although protons and neutrons in nuclei may have higher half-integer spins owing to energetic factors.
Atomic nuclei have a net nuclear spin, , which can have an integer or half-integer value. In atomic nuclei, the spins of protons are paired against each other but not with neutrons, and vice versa. Consequently, an even number of protons does not...
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探索混合磁纳米粒子:从原子自旋动力学模拟的洞察力.

Junais Habeeb Mokkath1, Remya Nair2, Mufasila Mumthaz Muhammed3

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概括

混合-加多 (NiGd) 纳米粒子显示可调节的磁性. Ni75Gd25纳米粒子在有限的温度下表现出增强的磁性性能,为先进的磁性应用提供了潜力.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 凝聚物质物理学 凝聚物质物理学
  • 纳米技术纳米技术

背景情况:

  • 结合稀土元素和过渡金属的二元纳米粒子提供了独特的磁性.
  • 了解有限温度磁性行为对于新的磁性应用至关重要.

研究的目的:

  • 研究尺寸和组成对混合NiGd纳米颗粒在有限温度下的磁性特性的影响.
  • 探索NiGd纳米粒子中的和磁化和旋转重定向动力学.

主要方法:

  • 使用了原子自旋动力学模拟.
  • 模拟涵盖了从4nm到16nm的纳米粒子大小.
  • 分析了组成的变化 (Ni75Gd25,Ni50Gd50,Ni25Gd75).

主要成果:

  • Ni75Gd25纳米粒子表现出增强的和磁化和磁性排序温度.
  • 增加的加多含量 (50%和75%) 导致和磁化和订制温度降低.
  • 尺寸和组成在有限的温度下显著影响磁性行为.

结论:

  • 加多含量是确定NiGd纳米粒子有限温度磁性特性的关键因素.
  • Ni75Gd25的成分显示出对高性能磁性材料的承诺.
  • 该研究提供了对设计先进磁性纳米材料的理论见解.