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在金属结合二维-MOF的表面电子特性驱动的电催化降解上

Ashakiran Maibam1,2,3, Ibrahim B Orhan2,4, Sailaja Krishnamurty1,3

  • 1Physical and Materials Division, CSIR-National Chemical Laboratory, Pune 411 008, India.

ACS applied materials & interfaces
|February 12, 2024
PubMed
概括

本研究探讨了二维金属有机框架 (MOFs) 作为降解反应 (NRR) 的单原子催化剂. Ti-TCPP MOF 显示出高NRR选择性和效率,使其成为可持续氨合成的有希望的电催化剂.

关键词:
NRR的选择性NRR的选择性密度函数理论 (DFT) 是指密度函数理论.电催化剂降解反应电催化剂降解反应动能屏障是一种动能屏障.限制可能的潜在限制.金属烯 (metalloporphyrin) 是一种金属烯.

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Though catalytic hydrogenation can reduce nitrobenzenes, the reduction is nonselective in the presence of other functional groups. For instance, if nitrobenzene contains an aldehyde group,...
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