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相关概念视频

Electrolytes: van't Hoff Factor03:08

Electrolytes: van't Hoff Factor

33.1K
Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
33.1K
Electrostatic Boundary Conditions in Dielectrics01:27

Electrostatic Boundary Conditions in Dielectrics

1.2K
When an electric field passes from one homogeneous medium to another, crossing the boundary between the two mediums imparts a discontinuity in the electric field. This results in electrostatic boundary conditions that depend on the type of mediums the field propagates through.
Consider a case where both the mediums across a boundary are two different dielectric materials. Recall that the electric field and electric displacement are proportional and related through the material's...
1.2K
Viscosity01:17

Viscosity

5.9K
When water is poured into a glass, it falls freely and quickly, whereas if honey or maple syrup is poured over a pancake, it flows slowly and sticks to the surface of the container. This difference in the flow of different kinds of liquids arises due to the fluid friction between the liquid layers and the liquid and the surrounding material. This property of fluids is called fluid viscosity. In this example, water has a lower viscosity than honey and maple syrup.
The SI unit of viscosity is...
5.9K
Viscosity of Fluid01:19

Viscosity of Fluid

413
Viscosity measures the resistance a fluid offers to flow and deformation. It results from internal friction between layers of fluid moving relative to one another. Dynamic viscosity, denoted by the Greek letter mu (μ), quantifies the force needed to move one fluid layer over another. For Newtonian fluids like water and air, the relationship between the shearing stress and the rate of shearing strain is linear, meaning their viscosity remains constant regardless of the applied stress.
413
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

63.0K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
63.0K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.7K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.7K

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相关实验视频

Updated: Jul 3, 2025

Generation and Control of Electrohydrodynamic Flows in Aqueous Electrolyte Solutions
08:41

Generation and Control of Electrohydrodynamic Flows in Aqueous Electrolyte Solutions

Published on: September 7, 2018

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在缩的电解质中,相关性诱导的粘性消散.

Paul Robin1

  • 1Laboratoire de Physique de l'École Normale Supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université Paris-Diderot, Sorbonne Paris Cité, Paris, France and Institute of Science and Technology Austria, 3400 Klosterneuburg, Austria.

The Journal of chemical physics
|February 13, 2024
PubMed
概括

我们发现离子-水结构和电解质粘度之间存在普遍联系. 这个模型准确地预测了缩盐溶液中的粘度变化,改善了我们对纳米级动态的理解.

科学领域:

  • 物理化学 物理化学
  • 解决方案化学 解决方案化学
  • 计算化学的计算化学

背景情况:

  • 溶解离子之间的静电相关性显著影响传输特性,如导电性和离子选择性.
  • 这些离子相关性对溶剂特性,特别是粘度的影响尚不清楚,目前的模型无法与实验数据相匹配.

研究的目的:

  • 开发一个模型,准确预测缩电解质溶液中的粘度变化.
  • 建立电解质溶液的微观结构与其宏观粘度之间的定量联系.

主要方法:

  • 利用随机密度函数理论 (SDFT) 准确捕捉电解质中的电荷波动和相关性.
  • 衍生出一种简单的分析表达式,用于缩电解质中的粘度校正.

主要成果:

  • 由此衍生的分析表达式在所有温度和盐度到和度的实验粘度数据上进行了定量预测.
  • 建立了连接液体结构因子与粘度校正的通用关系.

结论:

  • 这项研究通过将其直接与微观结构联系起来,为了解电解质粘度提供了突破性进展.
  • 这项工作为水和离子在高度缩和相关的溶液中的纳米级动态提供了新的见解.

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The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids
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The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids

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相关实验视频

Last Updated: Jul 3, 2025

Generation and Control of Electrohydrodynamic Flows in Aqueous Electrolyte Solutions
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Generation and Control of Electrohydrodynamic Flows in Aqueous Electrolyte Solutions

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Challenges in Rheological Characterization of Highly Concentrated Suspensions &#8212; A Case Study for Screen-printing Silver Pastes
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The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids

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