在缓慢冷却的性系统中有效地溶解纤维素,以及在分子层面上和尿素之间的相互作用模式
Shuo Ai1, Zhenhua Huang1, Wanguo Yu1
1College of Biological and Chemical Engineering, Guangxi University of Science and Technology, Liuzhou, 545006, China.
Carbohydrate research
|February 13, 2024
概括
在尿素NaOH中溶解微晶纤维素 (MCC) 通过缓慢冷却得到增强. 这种冷过程提高了MCC的溶解性,并有助于纤维素的修饰和机械加工.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 物理化学 物理化学
背景情况:
- 微晶纤维素 (MCC) 溶解是其加工的关键.
- 在像尿素-NaOH这样的溶剂系统中优化MCC溶解度对于工业应用至关重要.
研究的目的:
- 为了研究冷却条件对MCC溶解在尿素-NaOH系统中的影响.
- 在冷条件下阐明增强MCC溶解度背后的机制.
主要方法:
- 不同扫描热量计 (DSC) 检测热事件.
- 拉曼光谱和X射线光电子光谱 (XPS) 用于结构分析.
- 固态13C核磁共振 (NMR) 和密度函数理论 (DFT) 对结合模式的计算.
主要成果:
- 在缓慢冷却 (-0.3°C/分钟) 下,MCC的表面溶解率达到14%的重量.
- 在缓慢冷却过程中观察到显著的外热,表明MCC和溶剂之间的外热相互作用.
- NaOH和尿素在MCC中分裂了键,而溶解后形成了新的键.
- 证实了尿素和纤维素之间的双键结合模式.
结论:
- 缓慢冷却对于增强MCC在尿素-NaOH中的溶解至关重要,这归因于外热相互作用和高效扩散.
- 溶解过程是自发的,由于度下降和度增加,需要一个冷环境.
- 结果提供了关于纤维素修饰和通过优化溶解进行机械加工的宝贵见解.
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