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坚固的双网水凝具有快速的自我强化和低歇斯底里,基于高度纠的网络
Ruixin Zhu1, Dandan Zhu1, Zhen Zheng1
1School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China.
Nature communications
|February 13, 2024
概括
高度纠的双网水凝通过使用滑动物理纠来实现高性和低歇斯底里. 这种新的结构提供了卓越的机械性能和快速恢复,没有能量消耗机制.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
背景情况:
- 坚固的水凝通常依赖于能量消耗,但这可能会阻碍快速恢复.
- 在水凝中实现高性和低歇斯底里是很大的挑战,因为散射结构的恢复速度很慢.
研究的目的:
- 制造具有增强机械性能的高度纠的双网水凝.
- 为了克服水凝中性和歇斯底里斯之间的权衡.
- 探索物理纠作为交联机制的作用.
主要方法:
- 制造高度纠的双网水凝.
- 在第一个网络中使用物理纠作为主要交叉连接.
- 在拉伸过程中调查滑动纠结构.
主要成果:
- 实现了高拉伸强度 (~3 MPa) 和破裂能量 (8340 J m-2).
- 具有高抗应变强化能力 (47.5),含有90%的水分.
- 通过基于的能量存储获得了近100%的可逆性.
结论:
- 高度纠的双网水凝克服了性-歇斯底里斯的权衡,没有能量消散结构.
- 物理纠作为有效的交叉连接,使得统一的网络定向和高性能.
- 这项工作为使用纠结构用于先进的水凝应用提供了洞察力.
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