确定 perfluorooctanoic 酸的表面pKa的方法
Lila J Musegades1, Owen P Curtin2, Jenée D Cyran2
1Baylor University, Waco, Texas 76798, United States of America.
The journal of physical chemistry. C, Nanomaterials and interfaces
|February 14, 2024
概括
这项研究揭示了 perfluorooctanoic 酸 (PFOA) 如何改变水面的结构. 我们确定了其表面酸度 (pKa),为PFOA修复和气候模型提供了见解.
科学领域:
- 环境化学环境化学
- 表面科学是一门学科.
- 物理化学 物理化学
背景情况:
- perfluorooctanoic 酸 (PFOA) 是一种持久性有机污染物,具有毒性和生物积累性.
- 了解PFOA在水界面上的行为对于环境科学至关重要.
- 人们对PFOA在表面的物理化学性质的分子级细节了解甚少.
研究的目的:
- 为了研究PFOA和八酸 (OA) 在空气水表面的pH诱导的结构变化.
- 为了确定空气-水界面的PFOA和OA的表面pKa.
- 提供有关PFOA整治策略和气候建模的见解.
主要方法:
- 使用的特定表面技术:振动总数频率生成光谱 (SFG) 和表面张力计.
- 在广泛的pH值范围内研究了SFG光谱和表面活性.
- 应用了表面活动模型来分析实验数据.
主要成果:
- 确定了酸 (OA) 的表面pKa为3.8 ± 0.1.1.
- 确定 perfluorooctanoic 酸 (PFOA) 的表面表面 pKa 是 2.2 ± 0.2.2.
- 在空气-水界面上观察到PFOA和OA的明显的pH诱导的结构变化.
结论:
- 该研究阐明了PFOA和OA的表面行为作为pH的函数.
- 确定的表面pKa值为了解PFOA的环境命运提供了关键数据.
- 这些发现可以为修复PFOA污染的策略提供信息,并改善气候模型.
更多相关视频
09:04Identifying Per- and Polyfluorinated Chemical Species with a Combined Targeted and Non-Targeted-Screening High-Resolution Mass Spectrometry Workflow
Published on: April 18, 2019
12.5K
09:32A New Straightforward Method for Lipophilicity logP Measurement using 19F NMR Spectroscopy
Published on: January 30, 2019
14.4K
相关概念视频
Polyprotic Acids
29.2K
Acids are classified by the number of protons per molecule that they can give up in a reaction. Acids such as HCl, HNO3, and HCN that contain one ionizable hydrogen atom in each molecule are called monoprotic acids. Their reactions with water are:
29.2K
Acid and Bases: Ka, pKa, and Relative Strengths
26.7K
This lesson delves into a critical aspect of the relative strengths of acids and bases. The strength of an acid is evaluated by the acid dissociation into its conjugate base and a hydronium ion in water. The complete dissociation of a strong acid is confirmed with a very high concentration of hydronium ions. As a result, an incomplete dissociation process affirms a weak acid. Therefore, the equilibrium is in the forward direction for strong acids and backward for weak acids in these reactions.
26.7K
Solvating Effects
7.5K
An understanding of the solvating effect helps rationalize the relation between solvation and acidity of the compound. In addition, this also explains the relative stability of conjugate bases for compounds with different pKa values. This lesson details, in-depth, the principle of solvating effects. The strength of an acid and the stability of its corresponding conjugate base are determined using pKa values. This observed relationship is a consequence of solvation, which is the interaction...
7.5K
Acidity of Carboxylic Acids
7.0K
Carboxylic acids are the strongest organic acids. However, their acidic strength is much less than mineral acids like HCl. Carboxylic acids ionize in water and readily lose the hydroxyl proton to form a resonance-stabilized carboxylate ion.
7.0K
Calculating pH Changes in a Buffer Solution
53.3K
A buffer can prevent a sudden drop or increase in the pH of a solution after the addition of a strong acid or base up to its buffering capacity; however, such addition of a strong acid or base does result in the slight pH change of the solution. The small pH change can be calculated by determining the resulting change in the concentration of buffer components, i.e., a weak acid and its conjugate base or vice versa. The concentrations obtained using these stoichiometric calculations can be used...
53.3K
Titration of a Polyprotic Acid
96.6K
A polyprotic acid contains more than one ionizable hydrogen and undergoes a stepwise ionization process. If the acid dissociation constants of the ionizable protons differ sufficiently from each other, then the titration curve for such polyprotic acid generates a distinct equivalence point for each of its ionizable hydrogens. Therefore, titration of a diprotic acid results in the formation of two equivalence points, whereas the titration of a triprotic acid results in the formation of three...
96.6K
