在氧化物阴极中氧气空位化学.
Yu-Han Zhang1,2,3,4, Shu Zhang1,3,4, Naifang Hu1,3,4
1Qingdao Industrial Energy Storage Research Institute, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, P. R. China. majun@qibebt.ac.cn.
Chemical Society reviews
|February 14, 2024
概括
氧气空缺 (OV) 是过渡金属氧化物电池的关键缺陷,显著影响性能. 了解它们的形成和影响是开发用于二次电池的先进储能材料的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 二次电池对于清洁能源至关重要,氧化物阴极具有高容量.
- 氧气空缺 (OV) 是过渡金属氧化物电池中普遍存在的缺陷,影响性能.
研究的目的:
- 审查二次电池中的内在和阳离子氧化还原介导OVs的作用.
- 讨论OV的形成,进化和对氧化物阴极性质的影响.
主要方法:
- 近几十年来对二次电池中的OV研究的文献综述.
- 对OV形成和影响的热力学和动力学视角的分析.
主要成果:
- OVs显著影响氧化物阴极的热力学和运动性质.
- 散装和表面OV都在电池性能方面发挥着至关重要的作用.
结论:
- 对利用OV来提高电池能量密度和寿命的见解.
- 推进对OV的理解,以推动高性能电极材料的开发.
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