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一种多功能,生物来源的乳酸碳酸盐酸的新转化方法

Trinadh Kaicharla¹, Sangjun Lee¹, Ruiqin Wang¹

¹Department of Chemistry, 207 Pleasant St. SE, University of Minnesota, Minneapolis, MN 55455 USA.

ARKIVOC : free online journal of organic chemistry

|February 16, 2024

概括

来自植物的化合物被转化为新的乳衍生物. 这些新化合物显示出作为生物可再生单体的前景,用于先进的聚合技术,如可逆添加碎片链转移 (RAFT) 聚合.

科学领域:

有机化学有机化学
聚合物科学聚合物科学
绿色化学绿色化学

背景情况:

佛醇和伊塔康酸无水化物是植物衍生化合物.
这些化合物可以经历迪尔斯-阿尔德反应,形成含有基的乳碳酸盐酸.

研究的目的:

为了探索含有基的乳碳酸盐酸的衍生.
为了合成用于聚合的新生物可再生单体.

主要方法:

迪尔斯-阿尔德反应的furfuryl酒精和 itaconic无化物.
化,环氧化和活性化反应.
三甲酸催化化环开口与 (甲) 烯酸化物.

主要成果:

成功合成各种乳衍生物.
三种相关的烯酸或甲烯酸的形成.
识别潜在的生物可再生单体.

结论:

合成的烯酸和甲烯酸乙是可逆添加碎片化链转移 (RAFT) 聚合的有望候选者.
这项工作有助于从植物来源的资源中开发可持续的单体.

关键词:

含有乳糖的烯酸盐/甲烯酸盐.生物来源的单体.脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架,脚手架

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