聚散磁纳米粒子在水表面的中等尺度自我组织
Victor Ukleev1, Artoem Khassanov2,3, Irina Snigireva3
1Helmholtz-Zentrum Berlin für Materialien und Energie, D-14109 Berlin, Germany.
The Journal of chemical physics
|February 16, 2024
概括
多分散的氧化铁纳米粒子在水面上自组成有序的中晶集群. 纳米粒子尺寸分布影响了格子常数和内部集群结构.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术 纳米技术
- 表面化学 表面化学
背景情况:
- 朗穆尔的电影为研究纳米粒子自组装提供了一个平台.
- 了解纳米粒子排序对于开发先进材料至关重要.
研究的目的:
- 调查Langmuir电影中的多分散氧化铁纳米颗粒的自我排序.
- 描述纳米粒子集群和中晶体的形成和特性.
主要方法:
- 在现场的X射线散射 (反射计和放牧发生率小角度X射线散射)
- 表面压力面积异热分析
- 布鲁斯特角显微镜的使用方法
- 兰穆尔 - 谢弗尔转会转会
- 扫描电子显微镜扫描电子显微镜
- 两极化的中子反射测量
主要成果:
- 单层形成通过X射线反射测量证实.
- 观察到与平均粒子大小相匹配的短距离相关性.
- 粒子在零压力下形成亚微米集群,在压缩时合并.
- 长距离的顺序被揭示:六角格子中的圆形集群.
- 格子常数取决于粒子大小分布 (平均值和宽度).
- 观察到集群内的内部尺寸分离 (中心较大的粒子).
结论:
- 多聚散纳米粒子自组织成具有可调节性质的中晶体.
- 颗粒大小分布对自组装过程和由此产生的结构产生重大影响.
- 获得了纳米粒子层磁化概况的洞察力.
更多相关视频
相关概念视频
Potential Due to a Magnetized Object
924
Magnetic dipoles in magnetic materials are aligned when placed under an external magnetic field. For paramagnets and ferromagnets, dipole alignment occurs in the direction of the magnetic field. However, the dipoles align opposite to the field in the case of diamagnets. This state of magnetic polarization due to the external field is called magnetization. Magnetization is defined as the dipole moment per unit volume. It plays a similar role to polarization in electrostatics.
The vector...
The vector...
924
Magnetic Susceptibility and Permeability
2.9K
In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
2.9K
The Colloidal State
189
The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called...
189
Other Unique Bacteria
578
Magnetic bacteria exhibit a directed movement called magnetotaxis, driven by structures called magnetosomes. These magnetosomes consist of chains of magnetic particles made of either magnetite (Fe₃O₄) or greigite (Fe₃S₄) and are organized in a linear conformation by a protein scaffold within invaginations of the cell membrane. The bacteria align along the north–south magnetic field lines, much like a compass needle. They are typically microaerophilic or anaerobic...
578


