固体基质性质对玻璃成型支膜中的空间异质激活动态的影响
Anh D Phan1,2, Kenneth S Schweizer3
1Faculty of Materials Science and Engineering, Phenikaa University, Hanoi 12116, Vietnam.
The Journal of chemical physics
|February 16, 2024
概括
这项研究模拟了流体-基板合如何影响玻璃膜动态,揭示了接口如何影响局限系统中的放松时间和过渡温度.
科学领域:
- 材料科学 材料科学 材料科学
- 物理化学 物理化学
- 统计力学 统计力学
背景情况:
- 薄膜中的玻璃过渡动态受界面的影响.
- 流体-基板合和蒸汽接口对分子运动产生竞争效应.
- 了解这些影响对于设计纳米级材料至关重要.
研究的目的:
- 扩展现有的理论,以考虑放松时间和玻璃过渡温度的空间梯度.
- 为了研究可变流体-基板合在有限厚度薄膜中的影响.
- 在膜动态上分析固体-液体和蒸汽接口之间的相互作用.
主要方法:
- 使用力级弹性集体非线性朗格温方程理论.
- 建模表面动态自由能量格约束及其空间转移.
- 将理论应用于硬球体流体和聚合物化物.
主要成果:
- 流体-基板合显著影响动态梯度和薄膜平均数量.
- 蒸汽和固体界面效应之间的干扰决定了动态,包括一个散装类区域的潜在消失.
- 该研究确定了对薄膜叠加近似的准确性和失败的条件.
结论:
- 该理论为理解在有限几何形状下形成玻璃的液体的界面效应提供了一个框架.
- 结果突出了流体-基板相互作用在确定纳米级动力学中的关键作用.
- 这些发现对设计和预测纳米限制下材料的行为有影响.
相关概念视频
Polymer Classification: Crystallinity
3.1K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
3.1K
Total Voids in Concrete
1.4K
Total voids in concrete encompass gel water volume, capillary pores, and entrapped air. Gel water (retained within the cement hydration products) and physically entrapped or adsorbed water are significant for the hydration process. For complete hydration, it's estimated that the space needed for the products of a cubic centimeter of cement doubles. Capillary pores constitute the unoccupied space within the hydrated cement paste, with their size largely influenced by the water-to-cement...
1.4K


