使用Acidithiobacillus thiooxidans提取铜的污水污泥的生物洗:优化和生态风险评估
S O Rastegar1, A Samadi1, P Ahmadnezhad1
1Department of Chemical Engineering, Faculty of Engineering, University of Kurdistan, Sanadaj, Iran.
Chemosphere
|February 16, 2024
概括
这项研究使用Acidithiobacillus thiooxidans从污水污泥中进行铜生物洗,实现了85.3%的回收率. 该过程还对污泥进行了排毒,使其安全处置,并改善了土壤质量.
科学领域:
- 环境微生物学 环境微生物学
- 生物技术是生物技术.
- 废物管理 废物管理
背景情况:
- 污水污泥由于含有重金属,造成了处理方面的挑战.
- 生物溶解为金属回收和污泥排毒提供了一个可持续的替代方案.
研究的目的:
- 使用Acidithiobacillus thiooxidans.优化从污水污泥中的铜 (Cu) 生物溶解.
- 评估生物洗污泥的排毒和土壤增强特性.
主要方法:
- 响应表面方法 (RSM) 以优化固体与液体的比率,初始硫和初始pH值.
- 使用缩小核心模型进行动力学研究.
- 毒性特征泄漏程序 (TCLP) 用于污泥分析.
- 种子发芽试验,以评估土壤的改善.
主要成果:
- 在优化条件下获得的最大Cu回收率为85.3% (S/L=0.16%),S0=8.2g/L,pH=1.4).
- 化学反应被确定为铜提取过程中的速度限制步骤.
- 生物化显著降低了重金属的化能力,达到监管处置限制.
- 生物洗污泥改善了土壤质量,提高了种子发芽和生长指数.
结论:
- 酸性菌类 thiooxidans 在铜回收和污泥排毒方面是有效的.
- 优化的生物化条件最大限度地回收铜,最大限度地减少环境风险.
- 生物洗污泥可以安全地处置,并有利地用于改善土壤特性.
相关概念视频
Bioremediation
18.4K
Bioremediation is the use of prokaryotes, fungi, or plants to remove pollutants from the environment. This process has been used to remove harmful toxins in groundwater as a byproduct of agricultural run-off and also to clean up oil spills.
18.4K
Extraction: Advanced Methods
447
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
447


