Tungstate 间接 NiFe 层状双氧化使得长期性海水氧化成为可能
Hefeng Wang1, Zixiao Li2, Shaohuan Hong3
1College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan, Shandong, 250014, China.
Small (Weinheim an der Bergstrasse, Germany)
|February 17, 2024
概括
这项研究通过结合酸盐来增强用于海水电解的铁层双氧化物 (NiFe LDH). 这促进了氧气的进化,提高了水生产的稳定性和海洋环境的效率.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 可再生能源可再生能源是可再生能源.
背景情况:
- 使用可再生电力的海水分裂是能系统的关键.
- 海水中的离子会导致阳极催化剂腐蚀,限制长期稳定性.
- 铁层双氧化物 (NiFe LDH) 是有效的氧气进化催化剂.
研究的目的:
- 为了提高NiFe LDH在性海水中氧气演变的性能和稳定性.
- 为了研究 tungstate 介质对 NiFe LDH 特性的影响.
- 为了使海水有效地从海水中产生气,用于储能.
主要方法:
- 合成 tungstate 间隔的 NiFe LDH.
- 在性海水中对催化剂性能进行电化学测试.
- 对氧气演变效率和反应机制的分析.
- 在高电流密度下进行长期稳定性测试.
主要成果:
- Tungstate 间隔剂显著提高了 NiFe LDH 的海水氧化性能.
- 实现高电流密度,近100%的氧气生成效率.
- 在350小时内表现出优异的长期稳定性,活性检测最小.
- 确定了氧气进化的晶格氧气机制.
结论:
- Tungstate 间接的 NiFe LDH 为海水电解提供了稳定高效的阳极催化剂.
- 这一进步支持利用海洋资源开发基于的能源系统.
- 这种材料对储存风能等可再生能源充满希望.
相关概念视频
Alkali Metals
19.3K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
19.3K
Corrosion
24.3K
The degradation of metals due to natural electrochemical processes is known as corrosion. Rust formation on iron, tarnishing of silver, and the blue-green patina that develops on copper are examples of corrosion. Corrosion involves the oxidation of metals. Sometimes it is protective, such as the oxidation of copper or aluminum, wherein a protective layer of metal oxide or its derivatives forms on the surface, protecting the underlying metal from further oxidation. In other cases, corrosion is...
24.3K
Titration of Polyprotic Base with a Strong Acid
795
The titration of a polyprotic base such as sodium carbonate with a strong acid such as hydrochloric acid results in two equivalence points on the titration curve. At the first equivalence point, the carbonate ions in the base are completely converted to bicarbonate ions. The second equivalence point corresponds to the complete conversion of bicarbonate ions to carbonic acid, which dissociates into carbon dioxide and water. The region before the first equivalence point corresponds to the...
795
Corrosion of Reinforcement
184
The corrosion of steel reinforcement within concrete is a process influenced by the material's inherent properties and external factors. The high pH level of around 13, provided by calcium hydroxide present in concrete, initially protects the steel reinforcement by promoting the formation of a passive iron oxide layer on its surface.
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
However, over time and under certain conditions like carbonation, chloride ingress, and cracking this protective state can be compromised. Steel has areas with...
184
Qualitative Analysis
22.3K
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
For instance, group IV...
22.3K
Ions as Acids and Bases
23.7K
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
23.7K


