酸盐离子间接的NiFe层状双氧化物作为性海水氧化过程中高度活性和稳定的电催化剂
Xiaoyan Wang1, Zixiao Li2, Shengjun Sun3
1College of Physics and Electronic Engineering, Chongqing Normal University, Chongqing 401331, Chongqing, China; College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, Shandong, China.
Journal of colloid and interface science
|February 17, 2024
概括
本研究介绍了一种用于海水电解的抗腐蚀策略,该策略使用酸盐离子插入-铁层双氧化物到泡上. 这种方法提高了阳极稳定性和活性,用于腐蚀性海水环境中的氧气演化反应.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 腐蚀科学 腐蚀科学
背景情况:
- 海水电解是可持续生产气的关键技术.
- 由于化物离子的阳极腐蚀限制了长期的氧气演变反应.
- 铁层双氧化物 (NiFe LDH) 是有前途的电催化剂,但容易受到化物攻击.
研究的目的:
- 为海水电解中的NiFe LDH阳极开发一种有效的抗腐蚀策略.
- 在氧化演化反应过程中改善NiFe LDH的稳定性和活性.
- 为了研究氧化盐离子介质在减轻离子腐蚀中的作用.
主要方法:
- 在泡上合成NiFe层状双氧化物 (NiFe-C2O42-LDH/NF) 通过酸盐离子间隔.
- 在性海水中进行电化学测试,以评估氧化演化反应的性能.
- 长期稳定性测试以评估阳极的耐用性.
主要成果:
- NiFe-C2O42-LDH/NF电极表现出了对化物离子的优良抗腐蚀性能.
- 在 337 mV 的超电位下,达到 1000 mA cm-2 的电流密度.
- 保持连续运行500小时,表现出显著的稳定性.
结论:
- 氧化离子间隙有效地保护NiFe LDH免受化物诱导的腐蚀.
- 拟议的战略显著提高了用于海水电解的NiFe LDH的活性和长期稳定性.
- 这一进步为从海水中生产更强大,更有效的气铺平了道路.
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