在温和的温度下,纤维素易于被超基基衍生的离子液溶解,使用有机溶剂作为辅溶剂
Yuhui Ci1, Yunqian Ma2, Tianying Chen1
1National Engineering Laboratory of Textile Fiber Materials and Processing Technology, Zhejiang Sci-Tech University, Hangzhou 310018, China.
Carbohydrate polymers
|February 17, 2024
概括
将有机辅溶剂添加到可持续的离子液体 (SIL) 中,可以在较低的温度下有效地溶解纤维素. 甲基二硫氧化物 (DMSO) 显示出最佳性能,增强纤维素的溶性,并使先进的再生纤维素材料的生产成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
- 聚合物化学 聚合物化学
背景情况:
- 高效的纤维素利用对于从可再生资源生产高价值化学品和材料至关重要.
- 低温纤维素溶解是其可持续加工的一个关键挑战.
研究的目的:
- 调查近极有机溶剂作为与DBU衍生的离子液体 (SIL) 作为辅溶剂的潜力,用于低温纤维素溶解.
- 了解辅溶剂对纤维素溶解度,溶解以及再生纤维素的特性的影响.
主要方法:
- 实验性的溶解和再生纤维素.
- 密度函数理论 (DFT) 的计算.
- 分子动力学 (MD) 模拟.分子动力学 (MD) 模拟.
主要成果:
- 有机辅溶剂显著降低了纤维素溶解温度,增加了溶解度.
- 40%重量%二甲基硫氧化物 (DMSO) 证明了与SIL的最有效的协同作用,在75°C达到14.6%重量%的纤维素溶解度.
- 同溶剂类型影响再生纤维素的微观结构和化学结构.
结论:
- 共同溶剂有效地增强使用SILs的低温纤维素溶解.
- DMSO显示出卓越的性能,作为一种与SIL.一起溶解纤维素的共同溶剂.
- 这些发现为制造高性能再生纤维素纤维提供了指导.
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