聚乙烯糖酸-乳酸) 作为一种多功能添加剂,用于调节聚乙烯乳酸的可混合性,结晶性和机械性质
Yinbiao Feng1, Cong Wang1, Junjiao Yang2
1State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Bioprocess, College of Life Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China.
ACS omega
|February 19, 2024
概括
新的聚乙烯糖酸-同乳酸 (PESL) 共聚合物增强了聚乳酸 (PLA) 的性. 含有15%重量的PESL的混合物在断裂时延长率增加了250%,改善了PLA.
科学领域:
- 聚合物化学 聚合物化学
- 材料科学 材料科学 材料科学
- 生物材料工程 生物材料工程
背景情况:
- 聚乳酸 (PLA) 在性能上表现出局限性,往往需要为更广泛的应用进行修改.
- 聚合物混合是一种成熟的方法,可以在经济上提高聚合物的性能.
- 开发完全基于生物的PLA硬化剂对于可持续材料至关重要.
研究的目的:
- 合成具有不同乳酸 (LA) 含量的聚乙烯糖酸-同乳酸 (PESL) 共聚合物.
- 评估PESL共聚合物的有效性作为聚乳酸 (PLA) 的硬化剂.
- 研究PLA/PESL混合物的可混合性和机械性能.
主要方法:
- 使用四氧化物 (TTP) 催化剂,对酸 (SA),乙烯糖醇 (EG) 和LA进行单工业化聚凝.
- 合成PESL共聚合物,其LA含量在20%至86%的重量范围内.
- 拉伸测试,扫描电子显微镜 (SEM),差分扫描热量计 (DSC) 和PLA/PESL混合物的动力机械分析 (DMA).
主要成果:
- 与纯PLA (<10%) 相比,含有15% PESL72的PLA/PESL混合物在断裂时显著增加了延伸 (250%).
- 在拉伸失效后,SEM分析显示了PLA和PESL相之间的增强界面粘附.
- DSC和DMA证实了PLA/PESL混合物的链流动性增加,表明性得到改善.
结论:
- PESL共聚合物通过增强界面粘附和链流动性,有效地增强聚乳酸 (PLA) 的硬性.
- 合成的PESL共聚合物完全是生物基的,并证明了PLA修改的工业可行性.
- 这些发现支持开发用于包装和其他应用的先进,硬化的PLA基材料.
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