双金属PCN-333具有调制结晶和多孔性结构,可高效地去除刚果红色
Boxi Li1, Xufeng Zhang1, Jing Shen1
1College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650092, China.
ACS omega
|February 19, 2024
概括
在不同温度下合成的双金属金属有机框架 (BMOFs) 显示出增强的刚果红色吸附. 优化的Fe/Al比率和合成条件产生了用于染料废水处理的高容量,可重复使用的吸附剂.
科学领域:
- 材料科学 材料科学 材料科学
- 环境化学环境化学
- 纳米技术 纳米技术
背景情况:
- 与单金属MOF相比,双金属金属有机框架 (BMOF) 为环境修复提供了增强的吸附性能.
- 了解合成参数 (如温度) 对BMOF结构和性能的影响,对于材料设计至关重要.
- 合成温度对BMOF结晶和多孔性的影响仍未得到充分研究.
研究的目的:
- 研究合成温度 (135°C和150°C) 和Fe/Al比率对PCN-333基BMOF的结构性质和刚果红 (CR) 吸附性能的影响.
- 评估通过合成的BMOFs去除CR的吸附能力,动力学和热力学.
- 评估最有效的BMOF吸附剂的可再生性和可重复使用性.
主要方法:
- 基于PCN-333的BMOF的溶热合成,在135°C和150°C时具有不同的Fe/Al比率.
- 使用分析晶体结构和特定表面积的技术,对合成的BMOF进行表征.
- 批量吸附实验以确定CR吸附能力,动力学 (Langmuir模型,伪二次动力学) 和热力学参数.
- 在三个周期内进行再生和可重复使用性测试.
主要成果:
- 合成温度和Fe/Al比率显著影响双金属PCN-333.3的晶体结构和特定表面积.
- Fe/Al-PCN-333-135 ((3:1) 和 Fe-PCN-333-150 实现了分别为 3233 mg/g 和 3933 mg/g 的异常高的 CR 吸附能力.
- 吸附遵循兰格穆尔模型和伪二阶动力学,表明内热化学吸附.
- 优化的BMOF在三个周期内表现出良好的可再生性和可重复使用性.
结论:
- 合成温度是定制BMOFs用于染料吸附的结构和性能的一个关键参数.
- 开发的Fe/Al-PCN-333材料具有卓越的CR吸附能力,性能优于许多现有的吸附剂.
- 这些BMOF是有希望的候选人,可以有效和可持续地处理含有染料的废水.
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