利格宁结构特征对基于利格宁的甲粘合剂性能的影响
Xinwen Xu1, Haiming Li1, Xing Wang1
1Liaoning Key Lab of Lignocellulose Chemistry and BioMaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light, Industry and Chemical Engineering, Dalian Polytechnic University, Dalian, 116034, China.
Macromolecular rapid communications
|February 20, 2024
概括
有机溶解性 (OL) 能够在性粘合剂中更高的替代,而不是硫酸 (SL) 和 kraft (KL). 这使得基于木质素的基 (LPF) 粘合剂具有更好的性能和性能,符合国家标准.
科学领域:
- 聚合物科学 聚合物科学
- 材料化学 材料化学
- 生物聚合物利用方法
背景情况:
- 第二个最丰富的生物聚合物 - - 氨酸,在工业上未得到充分利用.
- 不同的素生产方法产生不同的物理和化学性质.
- 工业素 (SL,KL,OL) 可能会在类粘合剂中取代.
研究的目的:
- 为了评估不同工业在甲 (PF) 粘合剂合成中的有效性.
- 研究素源对素基烯酸 (LPF) 粘合剂性能的影响.
- 促进工业金的商业利用.
主要方法:
- 对素硫酸盐 (SL),强力素 (KL) 和有机溶解素 (OL) 的结构分析.
- 在PF粘合剂合成中,用精选的素部分替代.
- 由此产生的基于素的基 (LPF) 粘合剂的表征 (粘度,自由甲,剪切强度).
主要成果:
- 有机溶解素 (OL) 呈现出较高的基基,较低的分子量,以及比SL和KL更具反应性的位点.
- 通过OL最大的替代达到70%w/w.
- OLPF粘合剂表现出卓越的性能,符合国家标准,粘度为960 mPa·s,自由甲为0.157%,剪切强度为1.84 MPa.
结论:
- 生产方法极大地影响了青素适用于粘合剂的应用.
- 有机溶性素 (OL) 是PF粘合剂中替代物的有希望的替代品.
- 开发的OLPF粘合剂提供更高的性能,并满足行业的要求.
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