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Updated: Jul 2, 2025

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在主动W位点优化电子密度,以促进光催化H2进化.

Jing Xu1,2, Xueqi Zhang1,2, Wei Yan1,2

  • 1School of Physics and Electronic Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, P. R. China.

Inorganic chemistry
|February 20, 2024
PubMed
概括

优化电子结构是高效光催化生产的关键. 新的W-WC-W2C共催化剂通过削弱中间键来增强的进化,从而促进H2生成.

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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