通过替代离子电池的P2/O3双相阴极材料
Yixu Zhang1, Jiarui Chen1, Ruijuan Wang1
1National Base for International Science & Technology Cooperation, National Local Joint Engineering Laboratory for Key Materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage & Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, China.
ACS applied materials & interfaces
|February 21, 2024
概括
在P2/O3混合阴极材料中的兴奋剂显著提高了离子电池 (SIB) 的容量. 这种方法提高了循环稳定性,并减轻了结构损坏,为先进的电池开发铺平了道路.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- P2型Fe-Mn氧化物是具有良好的容量离子电池 (SIB) 的成本效益高的阴极材料.
- 铜的修改改善了循环,但降低了特定容量.
- 混合P2/O3相为增强电池性能提供了潜力.
研究的目的:
- 为SIBs设计和合成一个高容量,稳定的阴极材料.
- 为了研究Mg兴奋剂对P2/O3混合相的影响.
- 通过控制的Mg合并来提高电化学性能.
主要方法:
- 在分层氧化物合成中进行受控的Mg兴奋剂.
- 制造P2/O3混合相复合材料.
- 电化学表征包括循环性能和速率能力测试.
主要成果:
- 胺兴奋剂激活阳离子氧化还原,增加特异性放电能力.
- 双相结构减轻了应变,并提高了自行车的稳定性.
- 在0.1°C下,Na0.67Cu0.2Mg0.1Fe0.2Mn0.5O2达到212.0mAhg-1的功率,在80次循环后保持88.1%.
- 观察到优异的高压稳定性.
结论:
- 用Mg合的P2/O3复合材料是SIBs的有希望的阴极材料.
- 这一战略提高了产能,循环稳定性和结构完整性.
- 这些发现为开发先进的SIB阴极材料提供了洞察力.
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