在砂基板上的环氧和聚尿素涂层的洞穴演变过程
Caisheng Huang1, Xiaolong He1, Jianmin Zhang1
1State Key Laboratory of Hydraulics and Mountain River Engineering, Sichuan University, Chengdu 610065, China.
Ultrasonics sonochemistry
|February 21, 2024
概括
添加一个环氧砂层显著提高了聚合物涂层对化侵蚀的抗性. 使用这种层的聚尿素涂层显示出对长时间冲击的优越耐用性,最大限度地降低了基板损坏.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物工程 聚合物工程
- 表面工程是什么?表面工程是什么?
背景情况:
- 聚合物涂层对于保护砂等基材免受环境退化至关重要.
- 在超声波化等条件下了解故障机制对于材料开发至关重要.
- 现有的涂层可能缺乏足够的抗压性,导致过早的故障.
研究的目的:
- 研究各种聚合物涂层结构在砂上的化侵蚀失效机制.
- 评估中间环氧砂层在提高涂层性能方面的作用.
- 为了比较环氧和聚尿素涂料的化阻力,有和没有中间层.
主要方法:
- 准备了三种不同的聚合物涂层结构:环氧 (MEP1),环氧与中间环氧砂 (MEP2) 和聚氨酸与中间环氧砂 (MPU).
- 进行了超声波化实验,以模拟侵蚀条件.
- 损坏的表面的特征是为了分析洞穴分布和演变.
主要成果:
- 中间环氧砂层通过增强能量吸收和延迟坑形成,显著提高了化阻力.
- 中间层的粘附性防止了基板侵蚀,即使表面涂层受损.
- 聚尿素涂层 (MPU) 呈现出极好的弹性-塑性变形,能够承受长时间的化冲击,并呈现最小的侵蚀.
结论:
- 加入中间环氧砂层是一种有效的策略,可以提高聚合物涂层的化阻力.
- 聚尿素涂层与中间环氧砂层相结合,提供了优越的耐用性和防空蚀侵蚀的保护.
- 这些发现为设计适用于苛刻应用的强大的聚合物涂层系统提供了宝贵的见解.
相关概念视频
Mortar Joint Deterioration in Masonry
117
Mortar joint deterioration is a significant concern in masonry structures, with water accumulation in the joints leading to damage from freeze-thaw cycles. The repeated expansion of water during freezing and its melting during thawing develop and propagate cracks in the masonry joints. Eventually, this leads to the spalling of mortar from the joints, loosening masonry units and weakening the structure. The deteriorated mortar joints are also vulnerable to moisture intrusion into the walls.
The...
The...
117
Porosity in Cement Paste
135
The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
The balance of water to cement in the mix is...
The balance of water to cement in the mix is...
135
Transition Zone
91
The transition zone in concrete is a critical area where aggregate meets cement paste, marked by a distinct porosity and weakness compared to the surrounding material. The adhesion around the aggregates is primarily due to Van Der Waals forces. The voids within this zone influence its robustness; initially, it is less durable than the surrounding bulk mortar due to larger voids. Initially, when concrete is compacted, a higher water-cement ratio near the aggregates leads to the formation of...
91
Efflorescence in Masonry
82
Efflorescence in masonry walls appears as a fluffy crystalline powder, often white, resulting from water-soluble salts within the masonry or mortar. When water penetrates the masonry, it dissolves these salts and brings them to the surface, where they are deposited upon evaporation of water.
While initial efflorescence is common post-construction and can be cleaned with water and a brush, in certain instances, efflorescence can reappear and gradually diminish over time as salts are leached out...
While initial efflorescence is common post-construction and can be cleaned with water and a brush, in certain instances, efflorescence can reappear and gradually diminish over time as salts are leached out...
82
Mortar Joints in Brick Masonry
113
Mortar joints play a critical role in brick masonry, filling the spaces between brick to bind them together and provide structural integrity and strength. The thickness of these joints is variable, typically ranging from less than one-fourth inch to over half an inch, based on structural needs and specific applications.
The process of joint tooling is implemented as the mortar begins to harden. This technique involves compacting and shaping the mortar to enhance both the appearance and the...
The process of joint tooling is implemented as the mortar begins to harden. This technique involves compacting and shaping the mortar to enhance both the appearance and the...
113
Mortar Properties
123
Mortar properties encompass a range of characteristics crucial for construction and masonry work, including workability, water retention, bond strength, durability, compressive strength, volume change, and appearance. Workability refers to mortar's ability to be easily applied and manipulated without sagging or falling off surfaces, which is important for efficient masonry unit placement and alignment. Water retention is essential to prevent the mortar from losing moisture too quickly to...
123


