硫酸盐兴奋剂促进化晶体的聚集
Tianyu Wang1,2,3, Yu Zhang1, Jing Qi1,2,3
1State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
Environmental science & technology
|February 22, 2024
概括
将硫酸盐添加到废水中会增加化沉,有助于化的去除. 然而,硫酸盐兴奋剂降低了化的纯度,需要仔细控制度,以有效地回收化物.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 水处理 处理水的方法
背景情况:
- 废水中的化物污染对环境和健康构成风险.
- 化沉是化去除和回收的关键方法.
- 了解影响化沉的因素对于优化水处理至关重要.
研究的目的:
- 为了研究共存的硫酸盐对化沉的影响.
- 阐明硫酸盐影响化颗粒特性和纯度的机制.
- 为了确定最佳的硫酸盐度,以有效地去除和回收化物.
主要方法:
- 有控制的降水实验,使用不同硫酸盐与化物的摩尔比率.
- 化聚合物的颗粒大小分析.
- 在线原子力显微镜测量粒子间的力.
- 在化晶体中对硫酸盐兴奋剂的分析.
主要成果:
- 低硫酸盐度促进了化沉.
- 硫酸盐使聚合颗粒团的大小从750nm增加到2000nm.
- 硫酸盐兴奋剂中和正电荷,减少排斥,并增加晶体之间的粘附 (1.62至2.46nN).
- 硫酸盐提高了沉效率和核化速率,但降低了化的纯度.
结论:
- 添加硫酸盐可以提高化沉效率,并减少废水中的化物损失.
- 硫酸盐兴奋剂对化的纯度产生负面影响,需要分离以获得高纯度回收.
- 调节高化物废水中的硫酸盐度对于有效的化物清除和回收至关重要.
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