氧化过程和我
1Eawag, Swiss Federal Institute of Aquatic Science and Technology, CH-8600 Duebendorf, Switzerland; ENAC, School of Architecture, Civil and Environmental Engineering, Ecole Polytechnique Fédérale, CH-1000, Lausanne, Switzerland.
Water research
|February 22, 2024
概括
化学氧化有效地去除水处理中的微污染物,但了解反应动力学和转化产品是关键. 超过30年的研究已经改善了流程管理和清洁水的应用.
科学领域:
- 环境化学环境化学
- 水处理技术水处理技术
- 氧化过程 氧化过程
背景情况:
- 化学氧化对于减少水中的微污染物至关重要.
- 早期的评估只关注目标化合物的去除,忽视了更广泛的影响.
- 了解反应动力学和转化产物对于过程可行性至关重要.
研究的目的:
- 总结了30多年的水处理化学氧化研究.
- 要突出评估过程效率的演变,而不仅仅是简单的减排.
- 讨论管理化学氧化过程的复杂性和进步.
主要方法:
- 使用二次速率常数进行动力分析.
- 量化结构-活动关系 (QSAR) 用于预测反应性.
- 转化产品的形成和毒性的评估.
- 评估氧化剂反应与水矩阵组件,如溶解有机物 (DOM).
主要成果:
- 现在可以使用第二阶级利率常数的广泛数据库.
- QSAR模型能够对缺乏实验数据的化合物进行预测.
- 由于DOM (>99%) 的高氧化剂消耗,化学氧化过程往往是低效的.
- 消毒副产品 (DBP) 的形成是一个重大问题.
结论:
- 化学氧化过程是复杂的,但经过几十年的研究,人们已经很好地理解了.
- 优化应用在各种水处理系统 (饮用水,废水,再利用) 中是可行的.
- 需要继续进行研究,以解决转型产品影响和工艺效率的问题.
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