乙烯-三乙烯共聚物膜的制备,修改和应用
Zhangbin Liao1,2, Qian Wang1,2,3, Qiuyueming Zhou1,2,3
1State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.
Membranes
|February 23, 2024
概括
乙烯-三乙烯 (ECTFE) 膜可以使用热诱导相分离来制备. 表面修饰提高了它们在各种应用中的性能,重点是绿色溶剂和未来的高性能膜开发.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 乙烯-三乙烯 (ECTFE) 提供优异的热,机械和耐腐蚀性.
- 传统的非溶剂诱导相分离 (NIPS) 对ECTFE膜制造具有挑战性.
- 为了满足特定应用的性能需求,ECTFE膜需要表面修改.
研究的目的:
- 提供关于ECTFE膜制备和修改的全面概述.
- 探索ECTFE膜应用的最新进展.
- 讨论高性能ECTFE膜的未来前景.
主要方法:
- 用于ECTFE膜制备的热诱导相分离 (TIPS).
- 调查TIPS适合的溶剂和加工温度.
- 表面修饰技术,包括移植修饰和氧化.
主要成果:
- 通过TIPS成功准备ECTFE微膜.
- 确定TIPS的关键参数 (温度,溶剂).
- 证明表面修改对于性能提升的有效性.
结论:
- TIPS是一种生产ECTFE膜的可行方法,特别是微过类型.
- 表面修改对于优化ECTFE膜功能至关重要.
- 未来的研究应该集中在绿色溶剂和高性能ECTFE膜的先进制备技术上.
相关概念视频
Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)
1.9K
Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
1.9K
Olefin Metathesis Polymerization: Overview
2.1K
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
2.1K


