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通过反应挤出提高高宁填充聚烯的机械性能
Ruichen Wang1, Xiangyu You1, Shijie Qi1
1College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science of Science & Technology, Xi'an 710021, China.
Polymers
|February 24, 2024
概括
这项研究增强了高素含量的聚烯 (PP),改善了机械性能,降低了成本和温室气体排放. 马氏无水化物移植聚烯 (MAPP) 兼容剂是实现与整洁PP相比性能的关键.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 可持续材料 可持续材料
背景情况:
- 聚烯 (PP) 是一种广泛使用的塑料,具有显著的环境影响.
- 纸制造的副产品,为可持续材料开发提供了机会.
- 高素填充的PP复合材料正在被探索作为更环保的替代品.
研究的目的:
- 研究将高素含量 (乙酸素和Kraft素) 纳入聚烯的情况.
- 为了评估胺无接种聚烯 (MAPP) 作为兼容剂对混合物性能的影响.
- 评估素填充PP复合材料的机械性能,成本效益和环境效益.
主要方法:
- 双螺丝挤出和注塑被用来制备PP/质混合物.
- 作为兼容剂,采用了不同含量和化流量指数 (MFI) 的化无接种聚烯 (MAPP).
- 进行了机械测试 (模块,热偏移温度) 和成本/温室气体 (GHG) 排放分析.
主要成果:
- 与乙酸素 (AAL) 相比,强力素 (KL) 在PP中显示出更好的分散性.
- 与含有≥0.8%重量%MA和60-100g/10分钟的MFI的MAPP实现了最佳的兼容性.
- PP/KL与40%重量%的素和10 pph的兼容剂混合,其机械性能与纯 PP相提并论,其模量和热偏移温度 (HDT) 增加.
结论:
- 高素填充的PP复合材料,特别是KL和优化的MAPP,为整洁的PP提供了可行的可持续替代品.
- 这些混合物实现了可比的机械性能,同时降低了约20%的生产成本和约40%的温室气体排放.
- 这项研究促进了木质素的价值化,并有助于经济高效,环保的塑料材料的开发.
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