从消费性塑料食品容器中释放的纳米塑料的检测通过电磁加热热溶解质谱仪
Ke Shi1, Hong Zhang2, Jikun Gao3
1School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, Heilongjiang, 150090, PR China; School of Marine Science and Technology, Harbin Institute of Technology at Weihai, Weihai, Shandong, 264209, PR China; State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin, Heilongjiang, 150090, PR China.
Analytica chimica acta
|February 24, 2024
概括
消费者食品容器释放纳米塑料进入饮食中. 使用电磁加热与热解质谱法 (Eh-Py-MS) 的新方法准确量化这些纳米塑料,揭示食品包装是主要暴露源.
科学领域:
- 环境科学 环境科学
- 分析化学 分析化学
- 材料科学 材料科学 材料科学
背景情况:
- 纳米塑料是食品中发现的新兴环境污染物.
- 目前用于纳米塑料量化的方法是不够的.
- 消费者塑料食品容器是纳米塑料的饮食来源.
研究的目的:
- 开发一种快速而准确的方法来识别和量化纳米塑料.
- 评估环境因素和塑料特性对检测的影响.
- 评估消费者塑料食品容器作为人类纳米塑料暴露的来源.
主要方法:
- 电磁加热与热解质谱学 (Eh-Py-MS) 结合.
- 使用一个紧的热解室,以提高效率和减少功率.
- 系统地检查了操作参数,并调查了影响因素,如尺寸,添加剂,湿酸和老化.
主要成果:
- 实现了聚乙烯纳米塑料的15.72 ng的检测极限.
- 证明环境因素 (湿酸,老化) 和塑料特性 (尺寸,添加剂) 不影响检测.
- 在食品包装上验证了该方法的高回收率 (87.5-110%) 和精度 (RSD ≤11.36%).
结论:
- 开发的Eh-Py-MS方法提供了快速可靠的纳米塑料量化.
- 消费者塑料食品容器是人类直接接触纳米塑料的重要来源.
- 该方法对环境和材料的变化具有稳定性,适用于现实世界样品.
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