具有量身定制的粒子间键的等级响应交替纳米聚合物
Huibin He1, Xiaoxue Shen1, Chongyang Yao1
1State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Metasurfaces for Light Manipulation, Department of Macromolecular Science, Fudan University, 200438, Shanghai, P. R. China.
Angewandte Chemie (International ed. in English)
|February 25, 2024
概括
研究人员从无机纳米粒子 (NP) 中创建了pH响应的纳米结构. 这些交替纳米聚合物 (ANCP) 具有可调节的特性,在生物传感和电子领域具有潜在的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 物理化学 物理化学
背景情况:
- 无机纳米粒子 (NP) 的自我组装对于创建先进材料至关重要.
- 控制二进制NP系统中的有序组合和属性存在重大挑战.
研究的目的:
- 从二元无机NP中开发分层的pH响应交替共聚物样纳米结构.
- 设计可编程NP组件的粒子间静电相互作用.
主要方法:
- 使用具有相反电荷的聚合物移植NP作为纳米级单体 (纳米体).
- 通过静电相互作用诱导共聚变成交替纳米共聚物 (ANCPs).
- 研究粒子间键长度和纳米结构稳定性的pH依赖性变化.
主要成果:
- 在水性介质中实现了对pH有分层反应的纳米结构 (ANCP).
- 在pH~7-10之间对ANCP"键"长度 (纳米间距离) 进行可逆控制,调整表面等离子体共振.
- 观察到ANCP在pH≥11时分解成二次/三次,在pH7恢复时重新组装.
结论:
- 成功地将二元无机NP转化为响应pH的ANCP.
- 开发的纳米结构具有可调节的特性和可逆的组装/拆卸.
- 潜在的应用包括生物传感,光学波导和电子设备.
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