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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
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访问合成FeIIIMnIV核心以建模生物异金属活性位点

Justin L Lee1, Saborni Biswas2, Joseph W Ziller1

  • 1Department of Chemistry, University of California-Irvine Irvine CA 92697 USA aborovik@uci.edu.

Chemical science
|February 26, 2024
PubMed
概括

研究人员合成了第一个合成FeIII-(μ-O) -MnIV复合物,模仿了关键的金属蛋白中间体. 这个复合体表现出质子合电子转移 (PCET) 活动,并提供了对异金属合因子偏好的见解.

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