使用枣种子作为天然吸附剂从废水中去除马六合绿;异热,动力学,热力学和批量吸附工艺设计
Faisal Hassan Sorour1, N M Aboeleneen2, N M Abd El-Monem3
1Chemical Engineering Department, Canal High Institute for Engineering and Technology, Suez, Egypt.
International journal of phytoremediation
|February 27, 2024
概括
枣子种子有效地从废水中去除马六合绿色染料. 这种农业废物为染料吸附提供了一个可持续的解决方案,由动力学和热力学研究证实.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 废物管理 废物管理
背景情况:
- 染料污染废水造成环境风险.
- 农业废弃物,就像枣子种子一样,是一个未充分利用的补救资源.
研究的目的:
- 为了评估日种子 (DS) 作为马六甲绿 (MG) 染料的吸附剂的有效性.
- 为了描述枣种子和优化吸附条件.
主要方法:
- 使用FTIR,SEM,BET和EDX进行了日种子的表征.
- 进行了批量吸附实验,以确定最佳pH值,吸附剂剂量,接触时间和温度.
- 应用了吸附同热法 (Langmuir, Freundlich, Temkin) 和动力模型 (伪二阶).
主要成果:
- 对于MG染料去除的最佳条件是pH5,0.1g吸附剂剂量,25°C和30分钟的接触时间.
- 弗洛伊德利希等热量最好地描述了吸附过程,表明一个异质的表面.
- 伪二次运动模型表明,粒子内部扩散是速度限制的.
结论:
- 枣种子是一种可行的,低成本的吸附剂,用于马拉绿色染料的去除.
- 吸附过程是自发的,外热的,涉及物理吸附和化学吸附.
- 用枣种子处理废水符合可持续废物管理原则.
相关概念视频
Extraction: Advanced Methods
447
Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
447
Precipitation and Co-precipitation
1.8K
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
1.8K
Voltammetry: Stripping Methods
220
Anodic Stripping Voltammetry (ASV), Cathodic Stripping Voltammetry (CSV), and Adsorptive Stripping Voltammetry (AdSV) are electrochemical techniques used to determine trace amounts of analytes in solution. These methods involve applying a potential to an electrode and measuring the resulting current.
Anodic Stripping Voltammetry (ASV)
ASV is used to determine metals and metalloids at trace levels. It involves two steps: deposition and stripping. First, a negative potential is applied to the...
Anodic Stripping Voltammetry (ASV)
ASV is used to determine metals and metalloids at trace levels. It involves two steps: deposition and stripping. First, a negative potential is applied to the...
220


