在正/负热膨胀核心/外中通过压抑的多声波放松进行反热灭升变发光:Yb/Ho@ScF3纳米粒子
Yilin Wang1,2, Jiahui Rui1, Hao Song1
1Institute of Advanced Materials (IAM), Nanjing Tech University, Nanjing 211816, China.
Journal of the American Chemical Society
|February 27, 2024
概括
我们开发了一个核心/外上转换发光系统, 这种方法通过减少网格振动造成的能量损失来提高发光效率.
科学领域:
- 材料科学
- 发光效应
- 纳米技术
背景情况:
- 热灭 (TQ) 是发光的主要限制,通常由多声波放松 (MPR) 引起.
- MPR与格子振动有关,并且可以受到外部压力的影响.
研究的目的:
- 设计一个可以抑制MPR并降低TQ的核心/外升级发光系统 (UCL).
- 通过对核心格子施加压力来实现反TQ或热增强的UCL.
主要方法:
- 核心/外结构的制造:α-NaYF4:Yb/Ln@ScF3 (Ln = Ho,Er,Tm).
- 使用具有相反热膨胀的材料 (正核心,负外).
- 研究外引起的压力对核心格子和发光特性的影响.
主要成果:
- 在加热时,ScF3外的负热膨胀抑制了α-NaYF4核心的正热膨胀.
- 这种抑制对核心格子施加压力,抑制MPR并减少TQ.
- 观察到抗TQ或热增强的UCL,表明发光效率有所提高.
结论:
- 一个新的核心/外UCL系统有效地通过外诱导的压力抑制热火.
- 这一战略为开发各种应用的高效发光材料提供了新的途径.
相关概念视频
Photoluminescence: Applications
395
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
395
Photoluminescence: Fluorescence and Phosphorescence
2.1K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
2.1K
Variables Affecting Phosphorescence and Fluorescence
501
Fluorescence and phosphorescence are essential phenomena in fields like analytical chemistry, biological imaging, and materials science, where they detect molecular properties and visualize cellular structures. Understanding the variables that influence these luminescent behaviors is crucial for maximizing accuracy and efficiency in their applications. These variables can broadly be grouped into chemical structure, solvent properties, and external conditions, each playing a distinct role in...
501


