与NHC结合的 (NHC-ligated nickel) ......II) 博酸盐复合物和盐
Martin S Luff1, Luis Walther1, Maik Finze1,2
1Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. u.radius@uni-wuerzburg.de.
Dalton transactions (Cambridge, England : 2003)
|February 28, 2024
概括
这项研究探讨了与N-异环碳素 (NHC) 结合的 (II) 博酸盐,揭示了它们作为反阴离子和协调结合体的多样性作用. 合成了新的 (II) 复合物和协调聚合物,展示了蓝酸盐化学的多功能性.
科学领域:
- 协调化学 协调化学
- 有机金属化学 有机金属化学
- 材料科学 材料科学 材料科学
背景情况:
- (II) 博酸盐 (CBs) 在他们的协调行为方面得到了探索.
- N-异环碳 (NHCs) 是过渡金属化学中的多功能联体.
研究的目的:
- 为了合成和表征新型NHC结合(II) 酸盐复合物.
- 为了研究烯酸盐的协调模式和结构多样性.
- 探索这些复合物的潜力,作为协调聚合物的构建块.
主要方法:
- (II) 酸盐的合成及其与不同硬质散体的NHC的反应.
- 盐转化反应涉及 (II) 化物和金属酸盐.
- 使用光谱技术和X射线晶体学进行表征.
主要成果:
- 形成罕见的同质四重NHC结合 (((II) 酸 ([Ni ((NHC) 4) 2+).
- 合成具有较大的NHCs的跨-[Ni(NHC) 2 ((CB) 2) 复合体.
- 一个三-NHC复合盐 [Ni(iPr2ImMe) 3(NC-BH2CN) ]][BH2(CN) 2 的分离.
- 产生单一和非替代的协调化合物.
- 观察NHC结合的酸盐复合物作为协调聚合物的构建块.
结论:
- 烯酸盐表现出多样化的协调化学,作为非协调或协调离子.
- 选择蓝酸盐和联体决定了由此产生的协调复合物和盐.
- 与NHC结合的酸盐复合物为新型协调材料提供了途径.
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