在固体粒子上滴滴形成的限制效应.
Alexander K Shchekin1, Liubov A Gosteva1, Tatiana S Lebedeva1
1Department of Statistical Physics, Saint Petersburg State University, Faculty of Physics, 7-9 Universitetskaya nab., St. Petersburg, 199034, Russia.
Langmuir : the ACS journal of surfaces and colloids
|February 28, 2024
概括
这项研究研究了超和蒸汽中固体粒子周围的滴滴形成. 封闭系统中的封闭效应会导致在开放系统中看不到的独特的平衡解决方案.
科学领域:
- 物理化学 物理化学
- 热力学是一种热力学.
- 统计力学 统计力学
背景情况:
- 固体粒子周围的滴滴形成在相位过渡中至关重要.
- 了解平衡解决方案是描述核和生长过程的关键.
- 通过比较封闭 (法典合奏) 和开放 (大法典合奏) 系统,可以了解封闭效应.
研究的目的:
- 为了研究平衡液滴溶液在超和蒸气中的球形粒子周围的数量和稳定性.
- 为了比较一个封闭系统 (正规集团) 和一个开放系统 (大正规集团) 的行为.
- 探索被关押对滴水形成的影响.
主要方法:
- 宏观热力学分析.
- 经典密度函数理论 (DFT) 具有正方形梯度近似和卡纳汉-斯塔林状态方程,用于完全可湿的粒子.
- 经典的DFT随机相近似和基本的测量理论对于一个很难被湿透的粒子.
主要成果:
- 在正规集体中,系统可以表现出一个或三个平衡解决方案,第三个解决方案来自限制.
- 分析揭示了完全可以被湿透的粒子与不能被湿透的粒子的不同行为.
- 对于具有少量分子的不易被湿透的粒子,观察到溶液打破球形对称性.
结论:
- 限制显著影响平衡液滴溶液的数量和稳定性.
- DFT提供了一种强大的工具,可以在分子层面研究滴滴形成,捕捉像对称性破坏这样的复杂现象.
- 这些发现有助于更深入地了解限制环境中的核和相变.
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