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Recrystallization: Solid–Solution Equilibria01:10

Recrystallization: Solid–Solution Equilibria

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Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
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Phase Transitions: Vaporization and Condensation02:39

Phase Transitions: Vaporization and Condensation

17.6K
The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase...
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Energetics of Solution Formation02:35

Energetics of Solution Formation

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The formation of a solution is an example of a spontaneous process, which is a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Formation of the solution requires the solute–solute and solvent–solvent...
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Precipitation Processes01:12

Precipitation Processes

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The experimental conditions in a gravimetric analysis should be optimized to maximize the particle size and purity of the obtained precipitate. Ideally, the concentration of the precipitating reagent should be low with effective stirring to maintain low relative supersaturation for the growth of large crystals. In homogeneous precipitation, the precipitant is slowly generated by a chemical reaction in the solution to avoid local reagent excesses. For example, urea decomposes gradually to...
446
Crystal Growth: Principles of Crystallization01:25

Crystal Growth: Principles of Crystallization

1.9K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
1.9K
Solvents01:12

Solvents

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A solvent is a substance, most often a liquid, that can dissolve other substances. Here, the substance being dissolved is called a solute. When a solvent and a solute combine, they form a solution - a homogenous mixture of both the solvent and the solute. Water is a universal biological solvent. Its polar structure allows it to dissolve many other polar compounds. The ability of water to dissolve is governed by a balance between water molecules binding to each other and binding to the solute.
A...
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由溶剂蒸发驱动的短暂核化.

René de Bruijn1,2, Jasper J Michels3, Paul van der Schoot1

  • 1Department of Applied Physics and Science Education, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.

The Journal of chemical physics
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概括

溶剂蒸发驱动同质晶体核,创造远离平衡的条件. 核化流量显示了延迟和降低的诱导时间,随着蒸发率的增加,偏离了稳定状态近似值.

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科学领域:

  • 物理化学 物理化学
  • 材料科学 材料科学 材料科学
  • 化学工程是化学工程的重要组成部分.

背景情况:

  • 同质的晶体核化对于材料制造至关重要.
  • 有机电子产品的液态制造涉及到远离平衡的条件.
  • 溶剂蒸发可以诱导溶液沉和核化.

研究的目的:

  • 在溶剂蒸发下理论上研究同质晶体核化.
  • 为了建模与有机电子制造相关的远离平衡条件.
  • 为了获得核化流量的分析表达式.

主要方法:

  • 使用了古典核化理论.
  • 用拉普拉斯变换和奇点扰动理论解决了动力主方程.
  • 分析结果与数值评估进行了比较.

主要成果:

  • 与准稳定状态近似相比,核化流量表现出滞后.
  • 滞后时间受到蒸发速度对抗效应的影响.
  • 一个通用的诱导时间随着蒸发率的增加而减少.

结论:

  • 溶剂蒸发显著影响核化动态.
  • 衍生的分析理论准确地描述了在短暂条件下的核化流量.
  • 这些发现为控制制造过程中的结晶提供了洞察力.