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Updated: Jul 2, 2025

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在中对谷物边界断裂的原子学研究
Jingyuan Yan1, Shun Kondo1, Bin Feng1,2
1Institute of Engineering Innovation, The University of Tokyo, Tokyo 113-8656, Japan.
Nano letters
|February 28, 2024
概括
陶中的颗粒边界断裂在原子层面上被理解. 在氧化粒边界的断裂路径上的较弱键会导致材料失效.
科学领域:
- 材料科学 材料科学 材料科学
- 陶工程 陶工程 陶工程
- 纳米技术纳米技术
背景情况:
- 颗粒边界 (GB) 断裂是多晶陶中的主要故障机制.
- 由于复杂的原子排列,理解GB断裂的原子化机制具有挑战性.
研究的目的:
- 为了研究在α-Al2O3 13粒边界沿着原子尺度裂传播行为.
- 阐明控制陶中的GB骨折的原子化机制.
主要方法:
- 使用现场传输电子显微镜 (TEM) 和扫描TEM.
- 结合实验观测与密度函数理论计算.
主要成果:
- 直接确定了沿GB核心的原子尺度断裂路径.
- 确定较弱的本地债券和较少的债券是GB断裂的原因.
- 观察到的断裂路径与理论计算一致.
结论:
- 提供了对沿谷物边界的裂传播机制的原子论见解.
- 这些发现对谷物边界工程和陶硬化策略有重大影响.
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