在SiO2层之间插入的聚乙烯氧化膜用于高温介电储能
Zhizhan Dai1, Jiangheng Jia1, Song Ding1
1Hefei National Research Center for Physical Sciences at the Microscale, Department of Physics, and CAS Key Laboratory of Strongly Coupled Quantum Matter Physics, University of Science and Technology of China, Hefei 230026, China.
ACS applied materials & interfaces
|February 28, 2024
概括
这项研究用SiO2层增强聚烯氧化物 (PPO) 介电膜,用于高温电容器. 新的SiO2/PPO/SiO2材料在高温下显示出更好的分解强度,能量密度和充放电效率.
科学领域:
- 材料科学 材料科学 材料科学
- 电气工程 电气工程
- 聚合物科学 聚合物科学
背景情况:
- 双轴定向聚烯 (BOPP) 电容器仅限于低温 (<105 °C).
- 聚乙烯氧化物 (PPO) 提供更好的耐热性,但在高电场下在125°C时,电荷-放电效率下降.
研究的目的:
- 为电容器开发一种高温介电材料.
- 为了提高基于PPO的介电物的性能,用于苛刻的应用.
主要方法:
- 使用磁铁喷射制造SiO2/PPO/SiO2复合膜的制造.
- 在高温下,分解强度,放电能量密度和充放电效率的表征.
- 评估长期稳定性和自我愈合特性.
主要成果:
- 在125°C时,SiO2/PPO/SiO2复合材料具有增强的分解强度 (552 MV/m) 和放电能量密度 (3.5 J/cm3).
- 电荷放电效率显著提高,在125°C时达到89%.
- 与BOPP相比,复合材料表现出优越的性能,即使在室温下,也表现出自我愈合的行为.
结论:
- 在高温电容应用中,SiO2/PPO/SiO2复合介电材料具有前景.
- 增强的性能使其能够在苛刻的环境中使用,例如混合动力电动汽车.
- 自愈能力为长期可靠性增加了显著的价值.
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