热固态环氧树脂机械反应中的非共价相互作用
Dipak Prasad1, Nilanjan Mitra1
1Hopkins Extreme Materials Institute and Department of Mechanical Engineering, Johns Hopkins University, Baltimore, Maryland 21218, United States.
非共价相互作用,特别是范德瓦尔斯力,主导着聚合物在张力和剪切下的反应. 键是了解环氧树脂中冲击负载行为的关键.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 机械工程 机械工程
背景情况:
- 聚合物中的自由体积显著影响其机械性能.
- 在聚合物自由体内存在非共价相互作用 (键,静电,范德瓦尔斯) .
- 耐热环氧树脂是关键的界面粘合剂.
研究的目的:
- 在各种负载条件下识别,描述和分析环氧树脂中非共价相互作用的演变.
- 在机械应力过程中区分非共价和共价相互作用的作用.
- 了解不同类型的非共价键如何影响材料在张力,剪切和冲击下的反应.
主要方法:
- 将耐热环氧树脂样品置于单轴张力,剪切和冲击负荷的条件下.
- 对非共价相互作用的全面识别和描述.
- 分析不同菌株级别的相互作用演变.
主要成果:
- 非共价相互作用在单轴张力中占主导地位,在共价键保持完整的情况下,切割压力高达50%,共价键保持完整.
- 范德瓦尔斯相互作用是压力和剪切中50%应变下的反应的主要贡献者.
- 键在材料的反应中起着重要作用,特别是在冲击负荷下.
结论:
- 非对应相互作用是环氧树脂在拉伸和剪切应力下机械行为的关键决定因素.
- 在中等应力下范德瓦尔斯力的主导地位突显了它们在粘合剂应用中的重要性.
- 了解在冲击负荷时键的独特影响对于预测材料故障和设计坚固材料至关重要.
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