在环境条件下液态水的电结
Giuseppe Cassone1, Fausto Martelli2,3
1Institute for Chemical-Physical Processes, National Research Council, Viale F. Stagno d'Alcontres 37, Messina, 98158, Italy. cassone@ipcf.cnr.it.
Nature communications
|February 29, 2024
概括
应用0.100.15V/Å的电场会导致水中的电结. 这个过程形成了一个新的铁电玻璃水 (f-GW) 阶段,影响化学物理和生物学.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
背景情况:
- 水在各种自然和技术环境中与电场相互作用.
- 自19世纪以来,用电场凝固水的电结概念一直在探索,但取得了有限的成功.
研究的目的:
- 研究在环境条件下在散装液体水中电结的可能性.
- 为了描述由外部电场引起的相位过渡.
主要方法:
- 使用了长时间的初始分子动力学模拟 (高达500 psi).
- 在环境条件下对水施加0.10至0.15V/Å的外部电场.
主要成果:
- 观察到水的电结成铁电无形相,称为铁电玻璃水 (f-GW).
- 过渡到f-GW发生在大约150200 ps后,这取决于场强度.
- 发现显著抑制了键网络波动和结构/动态停止.
结论:
- 在环境条件下提供了批量液态水电结的证据.
- 发现f-GW对基础化学物理,生物学和催化有潜在的影响.
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